Abstract
The reaction products of polyhexamethyleneguanidine hydrochloride with the Cu2+, Zn2+, and Ni2+ ions, which are the polyligand coordination compounds formed by polyguanidine and hydroxyl ligands, were studied using IR, UV, and ESR spectroscopy. The influence of the nature of the chelating agent on the structure of the complexes formed was revealed. Antibacterial properties of the synthesized complexes were assessed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Vointseva, I.I. and Gembitskii, P.A., Poliguanidiny — dezinfektsionnye sredstva i polifunktsional’nye dobavki v kompozitsionnye materialy (Polyguanidines: Disinfection Means and Polyfunctional Additives to the Composite Materials), Moscow: LKM-press, 2009.
Mashkovskii, M.D., Lekarstvennye sredstva (Pharmaceuticals), Khar’kov: Torsing, 1997.
Owsik, I. and Kolarz, B., Polymers, 2001, vol. 48, p. 169.
Nizhnik, V.V. and Nizhnik, T.Yu., Vopr. Khim. Khim. Tekhn., 2006, no. 6, p. 120.
Zhang, Y., Jiang, J., and Chen, Y., Polymers, 1999, vol. 40, p. 6189.
Tarasevich, V.A. and Makatun, V.N., Vesti Nats. Akad. Nauk Bel., Ser. Khim. Nauk, 2010, no. 3, p. 78.
Kukushkin, V.Yu. and Kukushkin, Yu.N., Teoriya i praktika sinteza koordinatsionnykh soedinenii (Theory and Practice of the Synthesis of Coordination Compounds), Leningrad: Nauka, 1990.
Skopenko, V.V. and Zub, V.Ya., Koordinationnaya khimiya (Coordination Chemistry), Kiev: Kiev Univ., 2002.
Shevelenko, S.V., Kuchko, A.A., and Belyasova, N.A., Trudy Bel. Gos. Tekh. Univ., 2010, vol. 18, no. 4, p. 290.
Zhang, L., Yao, S., and Guan, Y., Process Biochemistry, 2005, vol. 40, p. 189.
Bellamy, L.J., Infrared Spectra of Complex Molecules, Moscow: Inostrannaya Literatura, 1963.
Zheligovskaya, N.N. and Chernyaev, I.I., Khimiya kompleksnykh soedinenii (Chemistry of Complex Compounds), Moscow: Vysshaya Shkola, 1966.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Moscow: Mir, 1991.
Kauffman, J.W., Hauge, R.H., and Margrave, J.L., J. Phys. Chem., 1985, vol. 89, no. 16, p. 3541.
Makatun, V.N., Khimiya neorganicheskikh gidratov (Chemistry of Inorganic Hydrates), Minsk: Nauka i Tekhnika, 1985, p. 82.
Spektroskopicheskie metody v khimii kompleksnykh soedinenii (Spectroscopic Methods in the Chemistry of Complex Compounds), Vdovenko, V.M., Ed., Moscow: Khimiya, 1964.
Beilar, J., The Chemistry of Coordination Compounds, Moscow: Inostrannaya Literatura, 1960.
Zhivopistsev, V.P. and Selezneva, E.A., Analiticheskaya khimiya tsinka (Analytical Chemistry of Zinc), Moscow: Nauka, 1975.
Peshkova, V.M. and Savostina, V.M., Analiticheskaya khimiya nikelya (Analytical Chemistry of Nickel), Moscow: Nauka, 1966.
Rakitin, Yu.V., Larin, G.M., and Minin, V.V., Interpretatsiya spektrov EPR koordinatsionnykh soedinenii (Interpretation of ESR Spectra of Coordination Compounds), Moscow: Nauka, 1993.
Rosthauser, J.W. and Winston, A., Macromolecules, 1981, vol. 14, p. 538.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.A. Dobysh, N.V. Koktysh, V.A. Tarasevich, V.E. Agabekov, V.N. Makatun, L.I. Antonovskaya, N.A. Belyasova, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 11, pp. 1772–1777.
Rights and permissions
About this article
Cite this article
Dobysh, V.A., Koktysh, N.V., Tarasevich, V.A. et al. Synthesis and study of properties of the polyhexamethyleneguanidine complexes with the ions Cu2+, Zn2+, and Ni2+ . Russ J Gen Chem 82, 1764–1769 (2012). https://doi.org/10.1134/S1070363212110035
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363212110035