Abstract
Methods have been developed for the synthesis of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines. The yield of the target products has been improved via complexation with the corresponding methoxy derivatives and subsequent hydrolysis of the methoxy groups. Some physicochemical properties of substituted 9,10-dioxo-9,10-dihydroanthracene-2,3-dicarboxylic acids and tetraanthraporphyrazine metal complexes derived therefrom have been studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Borisov, A.V., Maizlish, V.E., and Shaposhnikov, G.P., Russ. J. Gen. Chem., 2005, vol. 75, no. 10, p. 1579.
The Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., San Diego: Academic, 2003, vol. 15.
Maizlish, V.E. and Shaposhnikov, G.P., Uspekhi khimii porfirinov (Advances in the Chemistry of Porphyrins), St. Petersburg: Nauch.-Issled. Inst. Khimii Sankt-Peterb. Gos. Univ., 2004, vol. 4, p. 327.
Simon, J. and Andre, J.-J., Molecular Semiconductors. Photoelectrical Properties and Solar Cells, Berlin: Springer, 1985.
Zhidkie crystally: diskoticheskie mezogeny (Liquid Crystals: Discotic Mesogens), Usol’tseva, N.V., Ed., Ivanovo: Ivanov. Gos. Univ., 2004.
Hiller, H. and Beck, F., FRG Patent no. 2 125 590, 1972; Chem. Abstr., 1973, vol. 78, no. 11.
Sakamoto, K. and Ohno, E., J. Soc. Dyers Colour., 1996, vol. 112, no. 12, p. 368.
Sakamoto, K. and Ohno, E., Dyes Pigm., 1998, vol. 37, no. 4, p. 291.
Ohno, E. and Sakamoto, K., J. Chem. Soc. Jpn., 1995, vol. 9, no. 5, p. 730.
Shaposhnikov, G.P., Kulinich, V.P., and Maizlish, V.E., Uspekhi khimii porfirinov (Advances in the Chemistry of Porphyrins), St. Petersburg: Nauch.-Issled. Inst. Khimii Sankt-Peterb. Gos. Univ., 1999, vol. 2, p. 190.
Gorelik, M.V., Khimiya antrakhinonov i ikh proizvodnykh (Chemistry of Anthraquinones and Their Derivatives), Moscow: Khimiya, 1983.
Borisov, A.V., Maizlish, V.E., and Shaposhnikov, G.P., Russ. J. Gen. Chem., 2005, vol. 75, no. 7, p. 1151.
Borisov, A.V., Maizlish, V.E., and Shaposhnikov, G.P., Russian Patent no. 2 277 098, 2006; Byull. Izobret., 2006, no. 15.
Borisov, A.V., Maizlish, V.E., and Shaposhnikov, G.P., Russian Patent no. 2 280 036, 2006; Byull. Izobret., 2006, no. 20.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Borisov, V.E. Maizlish, G.P. Shaposhnikov, A.B. Korzhenevskii, T.G. Shikova, V.V. Sokolova, O.I. Koifman, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 10, pp. 1742–1749.
For communication II, see [1].
Rights and permissions
About this article
Cite this article
Borisov, A.V., Maizlish, V.E., Shaposhnikov, G.P. et al. Tetraanthraquinonoporphyrazines: III. Synthesis and physicochemical properties of metal complexes of hydroxy-substituted tetraanthraquinonoporphyrazines. Russ J Gen Chem 82, 1740–1747 (2012). https://doi.org/10.1134/S1070363212100180
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363212100180