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Spectral and complex-forming properties of β-bromo-substituted porphyrins in N,N-dimethylformamide

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Abstract

Contributions of structural and electronic effects to the reactivity and chromophore properties of tetrapyrrole macrocycles modified by bromine atoms were revealed on the basis of the kinetic data on the complex formation of 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin with zinc(II) and copper(II) acetates in N,N-dimethylformamide, and also by measuring spectral characteristics of porphyrin ligands and zinc and copper porphyrinates.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. V. Mal’tseva, N. V. Chizhova & N. Zh. Mamardashvili

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  1. O. V. Mal’tseva
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  2. N. V. Chizhova
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  3. N. Zh. Mamardashvili
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Correspondence to O. V. Mal’tseva.

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Original Russian Text © O.V. Mal’tseva, N.V. Chizhova, N.Zh. Mamardashvili, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 7, pp. 1179–1184.

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Mal’tseva, O.V., Chizhova, N.V. & Mamardashvili, N.Z. Spectral and complex-forming properties of β-bromo-substituted porphyrins in N,N-dimethylformamide. Russ J Gen Chem 82, 1278–1283 (2012). https://doi.org/10.1134/S107036321207016X

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  • DOI: https://doi.org/10.1134/S107036321207016X

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