Skip to main content
SpringerLink
Log in

A molecular receptor based on the 2,3,7,8,12,13,17,18-octaethyl-21,23-dimethylporphyrin for detection of fluoride ions: Synthesis, spectral and complexation properties

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

2,3,7,8,12,13,17,18-Octaethyl-21-methylporphyrin and 2,3,7,8,12,13,17,18-octaethyl-22,23-dimethylporphyrin monotriflate based on the former were synthesized. Basic and complexing properties of these compounds were studied by the method of spectrophotometric titration in acetonitrile-perchloric acid and acetonitrile-tetrabutylammonium fluoride systems at 298 K. It was established that in the system of acetonitrile-perchloric acid the cationic forms of 2,3,7,8,12,13,17,18-octaethyl-21-methylporphyrin do not form complexes with fluoride ions, whereas 2,3,7, 8,12,13,17,18-octaethyl-22,23-dimethylporphyrin monotriflate forms complexes of 1:1 composition with the fluoride ions. The protonation constant of 2,3,7,8,12,13,17,18-octaethyl-21-methylporphyrin and the stability constant of the complex of 2,3,7,8,12,13,17,18-octaethyl-22,23-dimethylporphyrin with fluoride ions in acetonitrile at the standard temperature were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ivanova, Yu.B., Sheinin, V.B., and Mamardashvili, N.Zh., Zh. Obshch. Khim., 2007, vol. 77, no. 8, p. 1380.

    Google Scholar 

  2. Kruk, N.N., Starukhin, A.S., Ivanova, Yu.B., Sheinin, V.B., and Mamardashvili, N.Zh., Zh. Prikl. Spectr., 2007, vol. 74, no. 6, p. 750.

    Google Scholar 

  3. Kruk, N.N., Starukhin, A.S., Sheinin, V.B., Ivanova, Yu.B., and Mamardashvili, N.Zh., RF Patent 2345352, Byul. Izobret., no. 3, 27.01.2009.

  4. Ivanova, Yu.B., Kruk, N.N., Starukhin, A.S., and Mamardashvili, N.Zh., Ross. Khim. Zh., 2009, vol. 53, no. 2, p. 7

    Google Scholar 

  5. Ivanova, Yu.B., Churakhina, Yu.I., and Mamardashvili, N.Zh., Zh. Obshch. Khim., 2008, vol. 78, no. 4, p. 691.

    Google Scholar 

  6. Kruk, M.M., Starukhina, A.S., Mamardashvili, N.Zh., Mamardashvili, G.M., Ivanova, Yu.B., and Maltseva, O., J. Porphyrins Phthalocyanines, 2009, vol. 13, no. 11, p. 1148.

    Article  CAS  Google Scholar 

  7. Toldina, O.V., Ivanova, Yu.B., Mamardashvili, G.M., and Mamardashvili, N.Zh., Tetrahedron Lett., 2008, vol. 48, no. 43, p. 3752.

    Google Scholar 

  8. Ivanova, Yu.B. and Mamardashvili, N.Zh., Book of Abstracts, Topics in Supramolecular Chemistry, Leuven, Belgium, 2010, p. 27.

    Google Scholar 

  9. Ivanova, Yu.B., Sheinin, V.B., and Berezin, B.D., Koord. Khim., 2002, vol. 28, no. 2, p. 158–160.

    Google Scholar 

  10. Kulikova, O.M., Ivanova, Yu.B., Glazunov, A.V., Semeikin, A.S., and Mamardashvili, N.Zh., Zh. Obshch. Khim., 2011, vol. 81, no. 10, p. 1741.

    Google Scholar 

  11. Kulikova, O.M., Ivanova, Yu.B., Glazunov, A.V., Semeikin, A.S., and Mamardashvili, N.Zh., Zh. Obshch. Khim, 2011, vol. 81, no. 11, p. 1894.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    Yu. B. Ivanova & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    Dao Tkhe Nam, A. V. Glazunov & A. S. Semeikin

Authors
  1. Yu. B. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dao Tkhe Nam
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Glazunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Semeikin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. Zh. Mamardashvili
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. B. Ivanova.

Additional information

Original Russian Text © Yu.B. Ivanova, Dao Tkhe Nam, A.V. Glazunov, A.S. Semeikin, N.Zh. Mamardashvili, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 7, pp. 1173–1178.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanova, Y.B., Nam, D.T., Glazunov, A.V. et al. A molecular receptor based on the 2,3,7,8,12,13,17,18-octaethyl-21,23-dimethylporphyrin for detection of fluoride ions: Synthesis, spectral and complexation properties. Russ J Gen Chem 82, 1272–1277 (2012). https://doi.org/10.1134/S1070363212070158

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363212070158

Keywords

Search

Navigation