Skip to main content
SpringerLink
Log in

Protolytic and complexing properties of hetarylhydrazones derived from o-tosylaminobenzaldehyde

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

New ligand systems were synthesized by condensation of o-tosylaminobenzaldehyde with quinolin-2-ylhydrazine and 1-methyl-1H-benzimidazol-2-ylhydrazine. Acid-base properties of the resulting hetarylhydrazones and their complexing power toward bivalent copper, nickel, and cobalt ions were studied. The stability constants of the complexes were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Popov, L.D., Morozov, A.N., Shcherbakov, I.N., Tupolova, Yu.P., Lukov, V.V., and Kogan, V.A., Usp. Khim., 2009, vol. 78, no. 7, p. 697.

    Article  Google Scholar 

  2. Khimiya gidrazonov (The Chemistry of Hydrazones), Kitaev, Yu.P., Ed., Moscow: Nauka, 1977, p. 72.

    Google Scholar 

  3. Lukov, V.V., Dontsova, E.V., Posokhova, S.V., Kogan, V.A., and Popov, L.D., Koord. Khim., 2004, vol. 30, no. 11, p. 874.

    Google Scholar 

  4. Tupolova, Yu.P., Lukov, V.V., Kogan, V.A., and Popov, L.D., Koord. Khim., 2007, vol. 33, no. 4, p. 310.

    Google Scholar 

  5. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., and Kogan, V.A., Russ. J. Gen. Chem., 2007, vol. 77, no. 7, p. 1284.

    Article  CAS  Google Scholar 

  6. Popov, L.D., Sherbakov, I.N., Levchenkov, S.I., Tupolova, Y.P., Kogan, V.A., and Lukov, V.V., J. Coord. Chem, vol. 61, no. 3, p. 392.

  7. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., Kogan, V.A., and Tupolova, Yu.P., Russ. J. Gen. Chem., 2010, vol. 80, no. 3, p. 493.

    Article  CAS  Google Scholar 

  8. Popp, F.D., Eur. J. Med. Chem., 1989, vol. 24, no. 3, p. 313.

    Article  Google Scholar 

  9. Likhate, M.A. and Fernandes, P.S., Indian J. Chem., 1990, vol. 67, no. 10, p. 862.

    CAS  Google Scholar 

  10. Pellerano, C., Savini, L., and Massarelli, P., Farmaco Ed. Sci., 1985, vol. 40, no. 9, p. 645.

    CAS  Google Scholar 

  11. Sharma, V.K., Sriwatstava, S., and Sriwatstava, A., Pol. J. Chem., 2006, vol. 80, no. 3, p. 387.

    CAS  Google Scholar 

  12. Bard, M.Z., Mahmoud, M.A., Mahgoub, S.A., and Hozien, Z.A., Bull Pol. Acad. Sci. Chem., 1989, vol. 37, nos. 5–6, p. 185.

    Google Scholar 

  13. Ozaki, M., Daido, K., Yoshino, K., Nakagawa, M., and Suzuki, T., Technol. Rep. Osaka. Univ., 1992, vol. 42, no. 2101, P. 285.

    CAS  Google Scholar 

  14. Pervova, I.G., Melkozerov, S.A., Slepukhin, P.A., Lipunova, N.G., Barachevskii, V.A., and Lipunov, I.N., Russ. J. Gen. Chem., 2010, vol. 80, no. 5, p. 987.

    Article  CAS  Google Scholar 

  15. Bren, V.A., Minkin, V.I., Shelepenko, E.N., Dubonosov, A.D., and Bushkov, A.Y., Mendeleev Commun., 1991, no. 2, p. 72.

  16. Lygaitis, R., Getantis, V., and Grazulevicins, J.V., Chem. Soc. Rev., 2008, vol. 37, no. 4, p. 770.

    Article  CAS  Google Scholar 

  17. Katyal, M. and Dutt, Y., Talanta, 1975, vol. 22, no. 2, p. 151.

    Article  CAS  Google Scholar 

  18. Schilt, A.A., Wu, J.L., and Case, F.H., Talanta, 1975, vol. 22, nos. 10–11, p. 915.

    Article  CAS  Google Scholar 

  19. Schilt, A.A., Quinn, P.C., and Johnson, C.L., Talanta, 1979, vol. 26, no. 5, p. 373.

    Article  CAS  Google Scholar 

  20. Singh, R.B., Talanta, 1982, vol. 29, no. 2, p. 77.

    Article  CAS  Google Scholar 

  21. Going, I.E. and Pflaum, R.T., Anal. Chem., 1970, vol. 42, no. 9, p. 1098.

    Article  CAS  Google Scholar 

  22. Burlov, A.S., Garnovskii, A.D., Alekseenko, V.A., Mastryukov, A.E., Sergienko, V.S., Zaletov, V.G., Lukov, V,V., Khokhlov, A.V., and Porai-Koshits, M.A., Koord. Khim., 1992, vol. 39, no. 8, p. 859.

    Google Scholar 

  23. Burlov, A.S., Kuznetsova, L.I., Adamova, S.N., Kurbatov, V.P., Bondarenko, G.I., and Garnovskii, A.D., Russ. J. Gen. Chem., 2000, vol. 70, no. 5, p. 750.

    CAS  Google Scholar 

  24. Burlov, A.S., Ikorskii, V.N., Nikolaevskii, S.A., Koshchienko, Yu.V., Vlasenko, V.G., Zubavichus, Ya.V., Uraev, A.I., Vasil’chenko, I.S., Garnovskii, A.D., and Borodkin, G.S., Zh. Neorg. Khim., 2008, vol. 56, no. 10, p. 1677.

    Google Scholar 

  25. Bermejo, M.R., Sanmartin, J.A.M., Garcia-Deibe, M., Fondo, M., Novio, F., and Navarro, D., Inorg. Chim. Acta, 2003, vol. 347, no. 1, p. 53.

    Article  CAS  Google Scholar 

  26. Garnovskii, D.A., Guedes da Silva, M.F.C., Kopilovich, M.N., Garnovskii, A.D., Fransto da Silva, J.J.R., and Pombeiro, A.J.L., Polyhedron, 2003, vol. 22, no. 10, p. 1335.

    Article  CAS  Google Scholar 

  27. Garcia-Deibe, A.M., Matalobos, J.S., Fondo, M., Vazquez, M., and Bermego, M.R., Inorg. Chim. Acta, 2004, vol. 357, no. 9, p. 2561.

    Article  CAS  Google Scholar 

  28. Alekseenko, V.A., Burlov, A.S., Bogotin, B.M., Lukova, O.A., Nedzvetskii, V.S., and Garnovskii, A.D., Koord. Khim., 1991, vol. 17, no. 1, p.76.

    CAS  Google Scholar 

  29. Inczédy, J., Analytical Applications of Complex Equilibria, Budapest: Akad. Kiadó, 1976.

    Google Scholar 

  30. Beck, M.T. and Nagypal, I., Chemistry of Complex Equilibria, Budapest: Akad. Kiado, 1985.

    Google Scholar 

  31. Rossotti, F.J.C. and Rossotti, H., The Determination of Stability Constants and Other Equilibrium Constants in Solution, New York: McGraw-Hill, 1961.

    Google Scholar 

  32. Mahia, J., Maestro, M., Vazquez, M., Bermejo, M.R., Gonzalez, A.M., and Maneiro, M., Acta Crystallogr., Sect. C, 1999, vol. 55, no. 12, p. 2158.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Southern Federal University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    L. D. Popov, O. I. Askalepova, E. B. Kaimakan, Yu. P. Tupolova, I. N. Shcherbakov, V. V. Lukov, O. V. Maevskii & V. A. Kogan

  2. Southern Research Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov

  4. North Caucasian Zonal Research Veterinary Institute, Novocherkassk, Russia

    A. A. Zubenko

Authors
  1. L. D. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. I. Askalepova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. B. Kaimakan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. P. Tupolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. N. Shcherbakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. I. Levchenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. V. Lukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. V. Maevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. V. A. Kogan
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. A. S. Burlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. A. A. Zubenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. P. Tupolova.

Additional information

Original Russian Text © L.D. Popov, O.I. Askalepova, E.B. Kaimakan, Yu.P. Tupolova, I.N. Shcherbakov, S.I. Levchenkov, V.V. Lukov, O.V. Maevskii, V.A. Kogan, A.S. Burlov, A.A. Zubenko, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 7, pp. 1129–1134.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Popov, L.D., Askalepova, O.I., Kaimakan, E.B. et al. Protolytic and complexing properties of hetarylhydrazones derived from o-tosylaminobenzaldehyde. Russ J Gen Chem 82, 1233–1237 (2012). https://doi.org/10.1134/S1070363212070080

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363212070080

Keywords

Search

Navigation