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Binary system organic base-anode in the oxidative activation of hydrogen sulfide

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Abstract

Initiation of the reaction between hydrogen sulfide and aliphatic, aromatic, and heteroaromatic hydrocarbons in acetonitrile using the binary system organic base-anode is described. The reaction of hydrogen sulfide with nitrogen-containing organic bases is studied by means of cyclic voltammetry. The reaction of hydrogen sulfide with triethylamine leads to the formation of thiolate anion. The next step o reaction is electrochemical oxidation of the thiolate anion that to lead thiyl radical formation in situ thiyl radicals. In the presence of binary system on the basis of hydrogen sulfide aliphatic, aromatic, and heteroaromatic thiols and sulfides are formed at room temperature.

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Authors and Affiliations

  1. Astrakhan State Technical University, ul. Tatishcheva 16, Astrakhan’, 414025, Russia

    E. V. Shinkar’, A. O. Okhlobystin & N. T. Berberova

  2. Southern Scientific Center of Russian Academy of Sciences, ul. Chekhova 41, Rostov-on-Don, Russia

    I. V. Smolyaninov

Authors
  1. E. V. Shinkar’
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  2. I. V. Smolyaninov
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  3. A. O. Okhlobystin
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  4. N. T. Berberova
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Corresponding author

Correspondence to N. T. Berberova.

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Original Russian Text © E.V. Shinkar’, I.V. Smolyaninov, A.O. Okhlobystin, N.T. Berberova, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 5, pp. 705–708.

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Shinkar’, E.V., Smolyaninov, I.V., Okhlobystin, A.O. et al. Binary system organic base-anode in the oxidative activation of hydrogen sulfide. Russ J Gen Chem 82, 815–818 (2012). https://doi.org/10.1134/S1070363212050015

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  • DOI: https://doi.org/10.1134/S1070363212050015

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