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Synthesis and spectral properties of merocyanine dyes based on fluorene and its derivatives

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Abstract

The di-, tetra- and hexamethine merocyaninyes, the derivatives of fluorene, diphenyl 9H-fluorene-2,7-disulfonate, and bis(2,2,3,3,4,4,5,5-octafluoropentyl) 9H-fluorene-2,7-disulfonate, as well as the derivatives of the heterocycles of moderate (indolylidene and benzotiazolylidene), weak (benzo[c,d]indolylidene and 2,6-diphenylpyrane) and strong (2,6-diphenylpyridine) electron-donor properties were synthesized and their absorption spectra in solvents of different polarity were studied. The quantum-chemical analysis of electronic structure of the synthesized merocyanines was performed and the types of electronic transitions in them were found by the DFT and TDDFT methods with the B3LYP/6-31G(d,p) basis.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02094, Ukraine

    I. V. Kurdyukova, N. A. Derevyanko & A. A. Ishchenko

  2. Donetsk National Technical University, Donetsk, Ukraine

    D. D. Mysyk

Authors
  1. I. V. Kurdyukova
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  2. N. A. Derevyanko
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  3. A. A. Ishchenko
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  4. D. D. Mysyk
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Corresponding author

Correspondence to A. A. Ishchenko.

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Original Russian Text © I.V. Kurdyukova, N.A. Derevyanko, A.A. Ishchenko, D.D. Mysyk, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 4, pp. 617–633.

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Kurdyukova, I.V., Derevyanko, N.A., Ishchenko, A.A. et al. Synthesis and spectral properties of merocyanine dyes based on fluorene and its derivatives. Russ J Gen Chem 82, 703–719 (2012). https://doi.org/10.1134/S1070363212040172

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  • DOI: https://doi.org/10.1134/S1070363212040172

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