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Preparation and properties of two polymorphic modifications of β-hydroxysulfoxide of the pinane series

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Abstract

The oxidation was performed of 2-(6,6-dimethylbicyclo[3.1.1]hept-2-ylmethylsulfanyl)ethanol II synthesized by adding 2-mercaptoethanol to (−)-β-pinene in the presence of a Lewis acid. The sulfoxide obtained is present in two polymorphic structures with different physical properties, spectral characteristics, and fungicidal activity.

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Authors and Affiliations

  1. Kazan State Medical University, ul. Butlerova 49b, Kazan, Tatarstan, 420012, Russia

    A. V. Aref’ev, V. A. Startsev & L. E. Nikitina

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    O. A. Lodochnikova

  3. Butlerov Institute of Chemistry, Kazan, Tatarstan, Russia

    E. N. Klimovitskii & A. E. Klimovitskii

Authors
  1. A. V. Aref’ev
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  2. V. A. Startsev
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  3. L. E. Nikitina
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  4. O. A. Lodochnikova
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  5. E. N. Klimovitskii
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  6. A. E. Klimovitskii
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Additional information

Original Russian Text © A.V. Aref’ev, V.A. Startsev, L.E. Nikitina, O.A. Lodochnikova, E.N. Klimovitskii, A.E. Klimovitskii, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 3, pp. 447–452.

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Aref’ev, A.V., Startsev, V.A., Nikitina, L.E. et al. Preparation and properties of two polymorphic modifications of β-hydroxysulfoxide of the pinane series. Russ J Gen Chem 82, 440–445 (2012). https://doi.org/10.1134/S1070363212030139

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  • DOI: https://doi.org/10.1134/S1070363212030139

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