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Synthesis and structure of N-(2-silatranylethyl)imidazoles

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Abstract

Organosilicon imidazole derivatives containing a 2-silatranylethyl [N(CH2CH2O)3Si(CH2)2] group on the nitrogen atom were synthesized, and their steric and electronic structures, including the nature of interaction between the imidazole and silatrane fragments, were studied by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy.

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Correspondence to V. D. Sheludyakov.

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Original Russian Text © V.D. Sheludyakov, N.E. Kuz’mina, A.M. Abramkin, A.A. Korlyukov, D.E. Arkhipov, S.V. Loginov, D.A. Cheshkov, P. A. Storozhenko, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 12, pp. 2019–2028.

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Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M. et al. Synthesis and structure of N-(2-silatranylethyl)imidazoles. Russ J Gen Chem 81, 2468–2477 (2011). https://doi.org/10.1134/S1070363211120085

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  • DOI: https://doi.org/10.1134/S1070363211120085

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