Abstract
Organosilicon imidazole derivatives containing a 2-silatranylethyl [N(CH2CH2O)3Si(CH2)2] group on the nitrogen atom were synthesized, and their steric and electronic structures, including the nature of interaction between the imidazole and silatrane fragments, were studied by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy.
Similar content being viewed by others
References
Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M., Cheshkov, D.A., and Storozhenko, P.A., Zh. Obshch. Khim., 2011, vol. 81, no. 12, p. 2010.
Egorochkin, A.N., Voronkov, M.G., and Kuznetsova, O.V., Polyarizatsionnyi effekt v organicheskoi, elementoorganicheskoi i koordinatsionnoi khimii (Polarization Effect in Organic, Organometallic, and Coordination Chemistry), Nizhnii Novgorod: Nizhegorod. Univ., 2008.
Voronkov, M.G., Brodskaya, E.I., Belyaeva, V.V., and Lazareva, N.F., Izv. Ross. Akad. Nauk, Ser. Khim., 2001, no. 3, p. 725.
Puri, K.J., Singh, R., and Chahal, V.K., Chem. Soc. Rev., 2011, vol. 40, p. 1791.
Voronkov, M.G. and D’yakov, V.M., Silatrany (Silatranes), Novosibirsk: Nauka, 1978.
Allen, F.H., Kennard, O., Watson, D.G., Brammer, L., Orpen, A.G., and Taylor, R., J. Chem. Soc., Perkin Trans. 2, 1987, no. 12, p. S1.
Pauling, L., The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry, Ithaca: Cornel Univ., 1960, 3rd ed.
Emsley, J., Chem. Soc. Rev., 1980, vol. 9, no. 1, p. 91.
Steed, J.W. and Atwood, J.L., Supramolecular Chemistry, Chichester: Wiley, 2000. Translated under the title Supramolekulyarnaya khimiya, Moscow: Akademkniga, 2007, vol. 1, p. 52.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.D. Sheludyakov, N.E. Kuz’mina, A.M. Abramkin, A.A. Korlyukov, D.E. Arkhipov, S.V. Loginov, D.A. Cheshkov, P. A. Storozhenko, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 12, pp. 2019–2028.
Rights and permissions
About this article
Cite this article
Sheludyakov, V.D., Kuz’mina, N.E., Abramkin, A.M. et al. Synthesis and structure of N-(2-silatranylethyl)imidazoles. Russ J Gen Chem 81, 2468–2477 (2011). https://doi.org/10.1134/S1070363211120085
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363211120085