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Synthesis and structure of nitrocyclohexenylcarboxylates

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Abstract

The diene condensation of 3-nitro- and 3-bromo-3-nitroacrylates with 2,3-dimethyl-1,3-butadiene and isoprene obtained under the reaction condition from 3-methyl-3-thiolene-1,1-dioxide was investigated. The formed 6-nitro-3-cyclohexenylcarboxylates were subjected to the intramolecular transformation (dehydration and dehydrohalogenation) to give the corresponding nitrocyclohexadienyl- and arylcarboxylates. The structure of the obtained compounds was established from the IR, 1H NMR spectra and independent synthesis.

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Authors and Affiliations

  1. Herzen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    N. A. Anisimova, A. A. Kuzhaeva, G. A. Berkova & V. M. Berestovitskaya

Authors
  1. N. A. Anisimova
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  2. A. A. Kuzhaeva
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  3. G. A. Berkova
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  4. V. M. Berestovitskaya
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Correspondence to N. A. Anisimova.

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Original Russian Text © N.A. Anisimova, A.A. Kuzhaeva, G.A. Berkova, V.M. Berestovitskaya, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 9, pp. 1507–1514.

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Anisimova, N.A., Kuzhaeva, A.A., Berkova, G.A. et al. Synthesis and structure of nitrocyclohexenylcarboxylates. Russ J Gen Chem 81, 1845–1852 (2011). https://doi.org/10.1134/S1070363211090180

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  • DOI: https://doi.org/10.1134/S1070363211090180

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