Abstract
By the example of the condensation products of acetone with the simplest aromatic carbonyl compounds it was shown that the joint interpretation of mass spectrometric and chromatographic data in conjunction with a priori assumptions about the nature of the chemical structure allows the detection of the components of reaction mixtures that were not previously characterized by standard mass spectra or by retention indices on standard stationary phases. A necessary condition for solving such problems is creating a hypothesis about the sample composition that is possible for the expected products of the known organic reactions.
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Original Russian Text © I.G. Zenkevich, A.I. Ukolov, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 9, pp. 1479–1489.
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Zenkevich, I.G., Ukolov, A.I. Features of the chromatography-mass spectrometric identification of condensation products of the carbonyl compounds. Russ J Gen Chem 81, 1818 (2011). https://doi.org/10.1134/S1070363211090143
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DOI: https://doi.org/10.1134/S1070363211090143