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Comprehensive study of the process of formation of the ceramic material with the composition 1.5MgO·0.5RO·2Al2O3·5SiO2 [R = Mn(II), Fe(II), Cu(II), or Zn]

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Abstract

The results of the study of ceramic materials obtained by partial substitution of MgO in the 2MgO×2Al2O3×5SiO2 (cordierite) with transition metal oxides FeO, MnO, CuO and ZnO, are presented The modification of the magnesium-aluminosilicate system led to intensification of the phase formation and improved the ceramics properties. In the systems modified with the oxides basic by their chemical nature (MnO, FeO) solid solutions formed Mg2−y R y Al4Si5O18 (0.5 < y <1.5), which, according to X-ray analysis, are close to high-and low-temperature modifications of cordierite, where R is Mn(II) or Fe(II). The qualitative phase composition of the materials modified with oxides of amphoteric nature (ZnO, CuO) is characterized by the presence of silicate and aluminate solid solutions Mg1−x R x Al2O4 (0.25 < x < 0.75), where R is Cu(II) or Zn. The activation energies of the studied processes and standard heats of formation of products were determined.

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References

  1. Toropov, N.A., Barzakovskii, V.P., Lapin, V.V., and Kurtseva, N.N., Diagrammy sostoyaniya silikatnykh sistem. Troinye silikatnye sistemy (State Diagrams of Silicate Systems. Triple Silicate Systems), Leningrad: Nauka, 1972.

    Google Scholar 

  2. Godovikov, A.A., Izv. Akad. Nauk SSSR, Ser. Geol., 1977, no. 1, pp. 14–36.

  3. Balkevich, V.L., Tekhnicheskaya keramika (Thechnical Ceramic), Moscow: Stroiizdat, 1986.

    Google Scholar 

  4. Haufe, K., Reactions in Solid Substances and on Their Surface, part 2, Moscow: Inostrannaya Literatura 1963.

    Google Scholar 

  5. Budnikov, P.P. and Ginstling, A.M., Reaktsii v smesyakh tverdykh veshchestv (Reactions in Solid Mixtures), Moscow: Stroiizdat, 1965.

    Google Scholar 

  6. Tret’yakov, Yu.D., Tverdofaznye reaktsii (Solid Phase Reactions), Moscow: Khimiya, 1978.

    Google Scholar 

  7. Sharp, J.H., Brindley, G.W., and Narahari Achar, B.N., J. Am. Cer. Soc., 1966, vol. 49, p. 379.

    Article  CAS  Google Scholar 

  8. Edwad, A., J. Am. Cer. Soc., 1963, vol. 46, no. 8, p. 374.

    Article  Google Scholar 

  9. Brown, M., Dollimor, R., and Galvey, A., Reactions in Solid Mixtures, Moscow: Mir, 1983.

    Google Scholar 

  10. Spiridonov, V.P. and Lopatkin, A.A., Matematicheskaya obrabotka fiziko-khimicheskikh dannykh (Mathematical Treatment of Physico-Chemical Data), Moscow: Mosk. Gos. Univ., 1970.

    Google Scholar 

  11. Babushkin, V.I. Matveev, G.M., and Mchedlov-Petrosyan, O.P., Termodinamika silikatov (Thermodynamics of Silicates). Moscow: Stroiizdat, 1972.

    Google Scholar 

  12. Ivanova, L.I., Zh. Fiz. Khim., 1961, vol. 35, no. 9, p. 2120.

    CAS  Google Scholar 

  13. Landiya, N.A., Raschet vysokotemperaturnykh teploemkostei tverdykh neorganicheskikh veshchestv po standartnoi entropii (Calculation of High-Temperature Heat Capacity of Solid Inorganic Substances from Standard Entropy), Tbilisi: Publ. of Gruz. SSR, 1962.

    Google Scholar 

  14. Karapet’yants, M.Kh., Zh. Fiz. Khim., 1958, vol. 32, no. 8, p. 1763.

    Google Scholar 

  15. Karapet’yants, M.Kh., Osnovnye termodinamicheskie konstanty neorganicheskikh i organicheskikh veshchestv (Principal Thermodynamic Constants of Inorganic and Organic Substances), Moscow: Khimiya, 1968.

    Google Scholar 

  16. Termicheskie konstanty veshchestv (Thermodynamic Constants of Substances), 10 issues, Glusko, V. et al., Eds., Moscow: VINITI, 1966–1982. 1973, no. 4, pt. 1; 1971, no. 5; 1972, no. 6, pt.1; 1974, no. 7, pt. 1; 1979, no. 9.

    Google Scholar 

  17. Kratkii spravochnik fiziko-khimicheskikh velichin (Concise Handbook of Physico-Chemical Values), Ravdel’, A.A., Ed., Leningrad: Khimiya, 1983.

    Google Scholar 

  18. Volkov, A.I. and Zharskii, I.M., Bol’shoi khimicheskii spravochnik (Big Chemical Handbook), Minsk: Sovremennaya Shkola, 2005.

    Google Scholar 

  19. Salychits, O.I. and Orekhova, S.E., Trudy Bel. Gos. Tekh. Univ., Ser. 3: Neorg. Khim., 2009, no. 17, p. 12.

  20. Republic Belarus’ Patent no. 12848, 2009, Byull. Izobret., 2010, no. 1, p. 88.

  21. Khimicheskaya tekhnologiya keramiki (Chemical Technology of Ceramics), Guzman, I.Ya., Ed., Moscow: RIF “Stroimaterialy,” p. 203.

  22. Plyusnina, I.I., Infrakrasnye spektry silikatov (Infrared Spectra of Silicates), Moscow: Mosk. Gos. Univ., 1967.

    Google Scholar 

  23. Lazarev, A.N., Kolebatel’nye spektry i stroenie silikatov (Vibrational Spectra and Structure of Silicates), Leningrad: Nauka, 1968.

    Google Scholar 

  24. Vlasov, A.G. and Florinskaya, V.A., Infrakrasnye spektry neorganicheskikh stëkol i kristallov (Infrared Spectra of Inorganic Glass and Crystals), Leningrad: Khimiya, 1972.

    Google Scholar 

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Authors and Affiliations

  1. Belarussian State Technological University, ul. Sverdlova 13-A, Minsk, 220050, Belarus

    O. I. Salychits & S. E. Orekhova

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  1. O. I. Salychits
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  2. S. E. Orekhova
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Correspondence to O. I. Salychits.

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Original Russian Text © O.I. Salychits, S.E. Orekhova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 5, pp. 711–718.

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Salychits, O.I., Orekhova, S.E. Comprehensive study of the process of formation of the ceramic material with the composition 1.5MgO·0.5RO·2Al2O3·5SiO2 [R = Mn(II), Fe(II), Cu(II), or Zn]. Russ J Gen Chem 81, 799–806 (2011). https://doi.org/10.1134/S1070363211050021

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  • DOI: https://doi.org/10.1134/S1070363211050021

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