Skip to main content
SpringerLink
Log in

Electrochemical properties and spectrophotometry of membranes based on holmium tetraphenylporphyrinchloride

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Protolytic properties of holmium tetraphenylporphyrinchloride were studied by the method of two-phase spectrophotometric titration with potentiometric monitoring of pH of the medium. Apparent constants of the heterophase reaction of the exchange of an anion for the hydroxide ion were determined. It was found that the membranes based on holmium tetraphenylporphyrinchloride with dibutyl phthalate as a solvent-softener are selective to ions of alkaline earth metals (Ca2+ and Ba2+) in the region of pH > 7 over the concentration range from 1 up to 1×10−4 M. Selectivity coefficients were determined by two independent methods: the method of biion potentials and the method of mixed solutions. The found selectivity series coincides with traditional Hofmeister series for cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Porfiriny: spektroskopiya, elektrokhimiya, primenenie (Porphyrins: Spectroscopy, Electrochemistry, Application), Enikolopyan, N.S., Ed., Moscow: Nauka, 1987, p. 175.

    Google Scholar 

  2. Biesaga, M., Pyrzynska, K., and Trojanowicz, M., Elsevier Talanta, 2000. vol. 51, p. 209.

    Article  CAS  Google Scholar 

  3. Hofmeister, F., Arch. Exp. Pathol. Pharmakol., 1888, vol. 24, p. 247.

    Article  Google Scholar 

  4. Campo Dall’Orto, V., Carballo, R., and Hurst, J.A., Spectrochim. Acta, 2005, vol. 61, p. 2089.

    Article  Google Scholar 

  5. Chaniotakis, N.A., Chasser, A.M., and Meyerhoff, M.E., Anal. Chem., 1988, vol. 60, p. 188.

    Article  Google Scholar 

  6. Liu, J., Masuda, J., and Sekido, E., Electroanal. Chem., 1990, vol. 291, p. 67.

    Article  CAS  Google Scholar 

  7. Kibbey, C.E., Park, S.B., DeAdwyler, G., and Meyerhoff, M.E., Electroanal. Chem., 1992, vol. 335, p. 135.

    Article  CAS  Google Scholar 

  8. Gorski, L., Malinowska, E., and Meyerhoff, M.E., Elsevier. Talanta, 2004, vol. 63, p. 101.

    Article  CAS  Google Scholar 

  9. Malinowska, E., Niedziolka, J., Rozniecka, E., and Meyerhoff, M.E., Electroanal. Chem., 2001, vol. 514, p. 109.

    Article  CAS  Google Scholar 

  10. Kum-Chul Oh, Seon Mook Lim, Insook R. Paeng, Electroanal. Chem., 2001, vol. 506, p. 42.

    Article  CAS  Google Scholar 

  11. Steinle, E.D., Schaller, U., and Meyerhoff, M.E., Anal. Scien., 1998, vol. 14, p. 79.

    Article  CAS  Google Scholar 

  12. Malinowska, E., Niedziolka, J., and Meyerhoff, M.E., Anal. Chim. Acta, 2001, vol. 432, p. 67.

    Article  CAS  Google Scholar 

  13. Messick, S.M., Krishnan, K.K., Hulvey, M.K., and Steinle, E.D., Anal. Chim. Acta, 2005, vol. 539, p. 223.

    Article  CAS  Google Scholar 

  14. Leyzerovich, N.N., Shvedene, N.V., Blikova, Y.N., Tomilova, L.G., and Pletnev, I.V., Electroanalysis, 2001, vol. 13, p. 246.

    Article  CAS  Google Scholar 

  15. Valiotti, A.B., Shumilova, G.I., and Vasil’eva, O.E., Abstracts of Papers, I Mezhdunarodnaya konferentsiya po biokordinatsionnoi khimii (I Int. Conf. on Biocoordination Chemistry), Ivanovo, 1994, p. 110.

  16. Valiotti, A.B., Vasil’eva, O.E., Trofimov, M.A., and Shumilova, G.I., Abstracts of Papers, VII Mezhdunarodnaya konferentsiya po khimii porfirinov i ikh analogov (VII Int. Conf. on the Chemistry of Porphyrins and their Analogs), St. Petersburg, 1995, p. 155.

  17. Valiotti, A.B., Shumilova, G.I., and Druzina Z.E., Abstracts of Papers, VI Mezhdunarodnaya konferentsiya “Problemy sol’vatatsii i kompleksoobrazovaniya v rastvorakh” (VI Int. Conf. “ Problems of Solvation and Complex Formation in Solutions”), Ivanovo, 1995, p. 10.

  18. Valiotti, A.B., Shumilova, G.I., and Druzina, Zh.E., Zh. Obshch. Khim., 1997, vol. 67, no. 5, p. 533.

    Google Scholar 

  19. Zaitseva, A.V., Abstracts of Papers, II Nauchnaya Sessiya UNTsKh SPbGU (II Sci. Session of Teaching and Scientific Center of Chemistry of St. Petersburg State University), St. Petersburg, 1998, p. 61.

  20. Hattori Hiroyuki, Hoshino Mayumi, and Wakii Tomoyuki, Anal. Chem., 2004, vol. 76, p. 5056.

    Article  Google Scholar 

  21. Valiotti, A.B., Kopylova, E.A., and Abakumova, R.A., Zh. Obshch. Khim., 1995, vol. 65, no. 10, p. 1647.

    CAS  Google Scholar 

  22. Valiotti, A.B., Kopylova, E.A., and Abakumova, R.A., Zh. Fiz. Khim., 1995, vol. 69, no. 12, p. 2176.

    CAS  Google Scholar 

  23. Fizicheskaya Khimiya (Physical Chemistry), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1987.

    Google Scholar 

  24. Nikolskii, B.P. and Materova, E.A., Ionoselectivnye elektrody (Ion-Selective Electrodes), Leningrad: Khimiya, 1980.

    Google Scholar 

  25. Materova, E.A., Grekovich, A.L., and Didina, S.E., Electrochemistry, 1972, no. 8, p. 1829.

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. B. Valiotti, O. E. Vasil’eva, T. A. Starikova & G. I. Shumilova

  2. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    A. S. Semeikin

Authors
  1. A. B. Valiotti
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. E. Vasil’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. A. Starikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Semeikin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. I. Shumilova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. B. Valiotti.

Additional information

Original Russian Text © A.B. Valiotti, O.E. Vasil’eva, T.A. Starikova, A.S. Semeikin, G.I. Shumilova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 4, pp. 672–677.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Valiotti, A.B., Vasil’eva, O.E., Starikova, T.A. et al. Electrochemical properties and spectrophotometry of membranes based on holmium tetraphenylporphyrinchloride. Russ J Gen Chem 81, 762–767 (2011). https://doi.org/10.1134/S1070363211040256

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211040256

Keywords

Search

Navigation