Abstract
1,3,5-Tris[bis(η5-cyclopentadienyl)chlorovanadium]melamin is prepared in high yield by the reaction of N,N′-bis(trimethylsilyl)dicyandiamide with bis(η5-cyclopentadienylvanadium) dichloride in tetrahydrofuran. As side products, trimethylchlorosilane and cyclopentadiene formed. Reaction of N,N′-bis(trimethylsilyl) dicyandiamide with benzoyl chloride results in the formation of tris(benzoyl)melamin.
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Original Russian Text © A.S. Gordetsov, S.V. Zimina, S.V. Saprykina, L.B. Loginova, A.V. Piskunov, V.F. Ur’yash, E.M. Moseeva, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 4, pp. 565–569.
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Gordetsov, A.S., Zimina, S.V., Saprykina, S.V. et al. Reaction of N,N′-bis(trimethylsilyl)dicyandiamide with bis(η5-cyclopentadienylvanadium) dichloride. Russ J Gen Chem 81, 658–662 (2011). https://doi.org/10.1134/S1070363211040062
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DOI: https://doi.org/10.1134/S1070363211040062