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Alkylation and acylation of C-phosphorylated acetamidines involving CH-acidic methylene group

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Abstract

Reactions of sodium derivatives of C-phosphorylated acetamidines containing CH-acidic methylene group with alkyl and acyl halides were studied. The interaction occurs selectively to form the products of alkylation and acylation of methylene group, respectively. A convenient method for the synthesis of C-alkylated and C-acylated derivatives of C-phosphorylated acetamidines was developed.

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References

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    V. E. Shishkin, E. V. Mednikov, M. A. Shevchenko, O. V. Anishchenko & Yu. V. Popov

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  1. V. E. Shishkin
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  2. E. V. Mednikov
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  3. M. A. Shevchenko
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  4. O. V. Anishchenko
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  5. Yu. V. Popov
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Corresponding author

Correspondence to V. E. Shishkin.

Additional information

Original Russian Text © V.E. Shishkin, E.V. Mednikov, M.A. Shevchenko, O.V. Anishchenko, Yu.V. Popov, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 4, pp. 549–553.

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Shishkin, V.E., Mednikov, E.V., Shevchenko, M.A. et al. Alkylation and acylation of C-phosphorylated acetamidines involving CH-acidic methylene group. Russ J Gen Chem 81, 642–646 (2011). https://doi.org/10.1134/S1070363211040049

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  • DOI: https://doi.org/10.1134/S1070363211040049

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