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Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate

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Abstract

Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate (benzene, 20°C) involves the activated methylene group with intermediate formation of trioxo derivatives and is accompanied by decomposition of carbon skeleton. The oxidation products are carbon dioxide, carboxylic acids, and tert-butyl and peroxy esters derived from the latter.

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Authors and Affiliations

  1. Lobachevskii Nizhnii Novgorod State University, pr. Gagarina 23, Nizhnii Novgorod, 603950, Russia

    L. P. Stepovik, M. V. Gulenova, I. A. Kalacheva & A. Yu. Potkina

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  1. L. P. Stepovik
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  2. M. V. Gulenova
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  3. I. A. Kalacheva
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  4. A. Yu. Potkina
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Correspondence to M. V. Gulenova.

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Original Russian Text © L.P. Stepovik, M.V. Gulenova, I.A. Kalacheva, A.Yu. Potkina, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 3, pp. 454–462.

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Stepovik, L.P., Gulenova, M.V., Kalacheva, I.A. et al. Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate. Russ J Gen Chem 81, 550–558 (2011). https://doi.org/10.1134/S1070363211030182

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  • DOI: https://doi.org/10.1134/S1070363211030182

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