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New approach to the synthesis of tris(perfluoroalkyl)borane adducts with dialkylamines

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An Erratum to this article was published on 01 May 2011

Abstract

A convenient synthetic approach to the adducts (C n F2n+1)3BNHR2 (n = 2–4, 6; R = Me, Et) was developed, based on the reaction of lithium perfluoroalkyls with dichloro(dialkylamino)boranes at temperatures below −90°C. The target products can be synthesized with preparative yields of 50–90%.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090, Russia

    N. Yu. Adonin

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Bardin

  3. Paderborn University, Essen, Germany

    U. Flörke

  4. Duisburg-Essen University, Essen, Germany

    H. -J. Fron

Authors
  1. N. Yu. Adonin
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  2. V. V. Bardin
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  3. U. Flörke
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  4. H. -J. Fron
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Correspondence to N. Yu. Adonin.

Additional information

Original Russian Text © N.Yu. Adonin, V.V. Bardin, U. Flörke, H.-J. Fron, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 3, pp. 413–420.

An erratum to this article can be found at http://dx.doi.org/10.1134/S1070363211050252

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Adonin, N.Y., Bardin, V.V., Flörke, U. et al. New approach to the synthesis of tris(perfluoroalkyl)borane adducts with dialkylamines. Russ J Gen Chem 81, 509–516 (2011). https://doi.org/10.1134/S107036321103011X

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  • DOI: https://doi.org/10.1134/S107036321103011X

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