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Protonation and alkylation of organophosphorus compounds with trifluoromethanesulfonic acid derivatives

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Abstract

Protonation (alkylation) of triphenylphosphine, triethylphosphite, triphenylphosphine oxide, triethylphosphate, hexamethylphosporamide, and dimethylphosphite with trifluoromethanesulfonic acid, its bisimide, and methyl ester was studied and the corresponding 1H, 13C, 19F, 31P NMR spectra were analyzed.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    L. L. Tolstikova, A. V. Bel’skikh & B. A. Shainyan

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  1. L. L. Tolstikova
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  2. A. V. Bel’skikh
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  3. B. A. Shainyan
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Correspondence to L. L. Tolstikova.

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Original Russian Text © L.L. Tolstikova, A.V. Bel’skikh, B.A. Shainyan, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 3, pp. 377–383.

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Tolstikova, L.L., Bel’skikh, A.V. & Shainyan, B.A. Protonation and alkylation of organophosphorus compounds with trifluoromethanesulfonic acid derivatives. Russ J Gen Chem 81, 474–480 (2011). https://doi.org/10.1134/S1070363211030054

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