Skip to main content
Log in

Vapor formation and thermodynamic properties of the gallium-lead system melts

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A vapor composition and thermodynamic properties of melts of the gallium-lead system were studied by high-temperature mass-spectrometry. It was shown on the basis of thermodynamic calculations that Ga1−x Pb x melts are characterized by an appreciable positive deviation from the ideal behavior in the temperature range 780–1170 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Emsley, J., The Elements, Oxford: Clarendon Press, 1991, 2nd ed.

    Google Scholar 

  2. Vol, A.E. and Kagan, E.K., Stroenie i svoistva dvoinukh metallicheskikh system (Structure and Properties of Binary Metal Systems), Moscow: Nauka, 1976, vol. 3.

    Google Scholar 

  3. Glazov, V.M. and Kim, S.G., Dokl. Akad. Nauk SSSR, Ser. Fiz. Khim., 1986, vol. 290, no. 4, p. 873.

    CAS  Google Scholar 

  4. Ugai, Ya.A., Samoilov, A.M., Semenova, G.V., and Goncharov, E.G., Zh. Fiz. Khim., 1986, vol. 60, no. 1, p. 25.

    CAS  Google Scholar 

  5. Ugai, Ya.A., Goncharov, E.G., Semenova, G.V., and Lazarev, V.B., Fazovye ravnovesiya mezhdu fosforom, mysh’yakom, sur’moi i vismutom (Phase Equilibria between Phosphorus, Arsenic, Antimony, and Bismuth), Moscow: Nauka, 1989.

    Google Scholar 

  6. Volkov, B.A., Ryabova, L.I., and Khokhlov, D.R., Usp. Fiz. Nauk, 2002, vol. 172, no. 8, p. 875.

    Article  Google Scholar 

  7. Samoylov, A.M., Buchnev, S.A., Khoviv, A.M., Dolgopolova, E.A., and Zlomanov V.P., Material Science in Semiconductor Processing, 2003, vol. 6, nos. 5–6, p. 481.

    Article  CAS  Google Scholar 

  8. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu: Spravochnik (Energies of Breaking Chemical Bonds: Ionization Potentials and Electron Affinities: Handbook), Kondrat’ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

  9. Balducci, G., Gigli, G., and Meloni, G., J. Chem. Phys., 1998, vol. 109, no. 11, p. 4384.

    Article  CAS  Google Scholar 

  10. Termodinamicheskie svoistva individual’nykh veshchestv: Spravochnic (Thermodynamic Properties of Pure Substances: Handbook), Glushko, V.P., Ed., Moscow: Akad. Nauk SSSR, 1978–1984, vols. 1–4.

    Google Scholar 

  11. Paule, R.C. and Mandel, J., Pure Appl. Chem., 1972, vol. 31, no. 3, p. 397.

    Google Scholar 

  12. Mann, J.B., J. Chem. Phys., 1967, vol. 46, no. 5, p. 1646.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. I. Lopatin.

Additional information

Original Russian Text © A.M. Samoilov, A.V. Naumov, S.I. Lopatin, A.A. Zagorodnyi, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 1, pp. 29–34.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Samoilov, A.M., Naumov, A.V., Lopatin, S.I. et al. Vapor formation and thermodynamic properties of the gallium-lead system melts. Russ J Gen Chem 81, 27–32 (2011). https://doi.org/10.1134/S1070363211010051

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363211010051

Keywords

Navigation