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Some peculiarities of metal migration in the aerobic and anaerobic conditions in the surface water bodies

Russian Journal of General Chemistry volume 80, pages 2682–2693 (2010)Cite this article

Abstract

The results of research on metal migration (Mn, Cu, Zn, Pb, Cr) in the surface water bodies of the different type (the Kiev and the Kanev reservoirs of the Dnieper cascade, and Verbnoye and Telbin lakes of the Kiev city) in dependence on their oxygenous regime are considered. It was shown that the metal migration in the aerobic conditions is mainly directed from water thickness to bottom sediments. In contrast, the migration of metal compounds from bottom sediments in the anaerobic conditions is increased. Manganese is mostly in a form of free ions Mn2+ in the pore solutions, therefore, it migrates from bottom sediments in the greatest extent. The migration of other studied metals occurs in a much smaller extent and depends on the migration mobility of organic substances which they are bound to complexes. Migration mobility of copper, lead and chromium decreases essentially when the hydrogen sulphide is in the water of bottom layer. The data on a degree of metal binding to complexes and their chemical nature in water of reservoirs and lakes are given. The greater part of metals is found to be in complex compounds with humic substances in water of the Dnieper reservoirs, whereas in the lakes a share of neutral (mainly with carbohydrates) and cationic (mainly with protein-like substances) complexes essentially increases. The distribution of metals is explained by distinction in a component composition of dissolved organic matters in the reservoirs and in the lakes.

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References

  1. Denisova, A.I., Nakhshina, Ye.P., Novikov, B.I., and Ryabov, A.K., Donnye otlozhenia vodohranilich i ih vliyanie na kachestvo vody (Bottom Sediments of Reservoirs and their Infl uence on Water Quality), Kiev: Naukova Dumka, 1987.

    Google Scholar 

  2. Denisova, A.I., Timchenko, V.M., Nakhshina, Ye.P., Gidrologiya i gidrokhimiya Dnepra i ego vodokhranilisch (Hydrology and Hydrochemistry of the Dnieper River and its Reservoirs), Kiev: Naukova Dumka, 1989.

    Google Scholar 

  3. Martynova, M.V., Azot i fosfor v donnyh otlozheniyah ozer i vodohranilicsh (Nitrogen and Phosphorus in Bottom Sediments of Lakes and Reservoirs), Moscow: Nauka, 1984.

    Google Scholar 

  4. Linnik, P.N., in Gidroenergetika i okruzhayushchaya sreda (Hydro-Power Energy and the Environment), Kiev: Libra, 2004, pp. 219–236.

    Google Scholar 

  5. Linnik, P.M., and Zubenko, I.B., Lakes Reservoirs: Research Managem., 2000, vol. 5, p. 11.

    Article  Google Scholar 

  6. Linnik, P.N., Zhuravleva, L.A., Samoylenko, V.N., and Nabivanets, Yu.B., Gidrobiol. Zh., 1993, vol. 29, no. 1, p. 86.

    Google Scholar 

  7. Zhuravleva, L.A., and Linnik, P.N., Gidrobiol. Zh., 1989, vol. 25, no. 3, p. 69.

    Google Scholar 

  8. Linnik, P.N., Gidrobiol. Zh., 2006, vol. 42, no. 3, p. 97.

    CAS  Google Scholar 

  9. Mizandrontsev, I.B., Khimicheskie prozessy v donnyh otlozheniyah vodoemov (Chemical Processes in Bottom Sediments of Water Bodies) Novosibirsk: Nauka, Sibirskoe otdelenie, 1990.

    Google Scholar 

  10. Belkina, N.A., Sandman, O., and Ignatyeva, N.V., Ekol. Khim., 2006, vol. 15, no. 3, p. 174.

    Google Scholar 

  11. Linnik, P.N., Timchenko, O.V., Zubko, A.V., Zubenko, I.B., and Malinovskaya, L.A., Gidrobiol. Zh., 2008, vol. 44, no. 6, p. 94.

    CAS  Google Scholar 

  12. Vodohranilischa i ih vozdejstvie na okruzhayucshuyusredu (Reservoirs and their Influence on Environment), Moscow: Nauka, 1986.

  13. Linnik, P.N., Zubko, A.V., Zubenko, I.B., Ignatenko, I.I., and Malinovskaya, L.A., Gidrobiol. Zh., 2009, vol. 45, no. 1, p. 99.

    CAS  Google Scholar 

  14. Linnik, P.N. and Zubko, A.V., Ekol. Khim., 2007, vol. 16, no. 2, p. 69.

    Google Scholar 

  15. Linnik, P.N., Vasilchuk, T.A., and Zubko, A.V., Ekol. Khim., 2007, vol. 16, no. 3, p. 135.

    Google Scholar 

  16. Samanidou, V., Papadoyannis, I., and Vasilikotis, G., J. Environ. Sci. Health. A., 1991, vol. 26, no. 7, p. 1055.

    Article  Google Scholar 

  17. Bondareva, L.G., Kalyakina, O.P., and Bolsunovskiy, A.Ya., Zh. Ana. Khim., 2006, vol. 61, no. 4, p. 388.

    Google Scholar 

  18. Elkins, K.M. and Nelson, D.J., Coord. Chem.Rev., 2002, vol. 228, p. 205.

    CAS  Article  Google Scholar 

  19. Zeh, P., Kim, J.H., Marquardt, C.M., and Artinger, R., Radiochim. Acta, 1999, vol. 87, no. 1–2, p. 23.

    CAS  Google Scholar 

  20. Wilson, S.A., and Weber, J.H., Chem. Geol., 1979, vol. 26, no. 3, p. 345.

    CAS  Article  Google Scholar 

  21. Linnik, P.N., Vasilchuk, T.A., and Zaporozhets, O.A., Khim. Tehnol. Vody, 2003, vol. 25, no. 6, p. 549.

    CAS  Google Scholar 

  22. Nabivanets, B.I., Linnik, P.N., and Kalabina, L.V., Kineticheskie metody analiza prirodnyh vod (Kinetic Methods of the Analysis of Natural Waters), Kiev: Naukova Dumka, 1981.

    Google Scholar 

  23. Linnik, P.N., Leshchinskaya, A.A., and Nabivanets, B.I., Gidrobiol. Zh., 1989, vol. 25, no. 2, p 88.

    Google Scholar 

  24. Linnik, P.N. and Nabivanets, Yu.B., Gidrobiol. Zh., 1988, vol. 24, no. 1, p 68.

    CAS  Google Scholar 

  25. Kievskoe vodohranilicshe: gidrohimiya, biologiyaproduktivnost (Kiev Reservoir: Hydrochemistry, Biology and Productivity), Kiev: Naukova Dumka, 1972.

  26. Linnik, P.N., Gidrobiol. Zh., 1999, vol. 35, no. 2, p. 97.

    Google Scholar 

  27. Linnik, P.N., Vasilchuk, T.A., Perminova, I.V., Hatfield, K., and Hertkorn, N., NATO Science Series. IV: Earth and Environmental Series. Netherlands: Springer, 2005, vol. 52, p. 135.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Hydrobiology, National Academy of Sciences of Ukraine, Kiev, 04210, Ukraine

    P. N. Linnik

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Original Russian Text © P.N. Linnik, 2009, published in Ekologicheskaya Khimiya, 2009, Vol. 18, No. 3, pp. 129–141.

Peter Nikitovich Linnik, Dr. Sc. (Chem.), Prof., Head of Hydrochemical Department, Institute of Hydrobiology, National Academy of Sciences of Ukraine. Scientific areas of focus: analytical chemistry of objects of hydrosphere, hydrochemistry of surface water bodies, chemical pollution of natural waters.

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Linnik, P.N. Some peculiarities of metal migration in the aerobic and anaerobic conditions in the surface water bodies. Russ J Gen Chem 80, 2682–2693 (2010). https://doi.org/10.1134/S1070363210130025

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  • DOI: https://doi.org/10.1134/S1070363210130025

Keywords

  • Humic Substance
  • General Chemistry
  • Bottom Sediment
  • Dissolve Organic Matter
  • Dissolve Organic Matter