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Thermodynamic properties of silicate glasses and melts: VII. System MgO-B2O3-SiO2

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Abstract

Processes of evaporation and thermodynamic properties of glasses and melts of the system MgO-B2O3-SiO2 in the range of 1550–1800 K were studied for the first time by high-temperature mass-spectrometry. The resulting activities and Gibbs energies of components and also corresponding excess values point to negative deviations from ideal behavior and to the absence of immiscibility fields in glasses and melts of the system under study in the studied temperatures and concentration intervals.

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References

  1. Stolyarova, V.L., Lopatin, S.I., and Shilov A.L., Zh. Obshch. Khim., 2009, vol. 79, no. 9, p. 1422.

    Google Scholar 

  2. Zhang, P., Lou, H., Sui, Z., and Ma, R., Trans. Nonferrous Met. Soc. China, 1994, vol. 4, no. 4, p. 56.

    CAS  Google Scholar 

  3. Zhang, P.X., Zhang, Q., Wu, L., and Sui, Z., Z. Metallkunde, 1996, vol. 87, no. 1, p. 76.

    CAS  Google Scholar 

  4. Zhang, P., Sui, Z., Xie, S., and Ma, R., Youse Jinshu., 1998, vol. 50, no. 2, p. 63.

    CAS  Google Scholar 

  5. Peixin, Z., Xiugai, Z., and Shuiwei, X., Z. Metallkunde, 1998, vol. 89, no. 4, p. 267.

    Google Scholar 

  6. Cheynet, B., Chaud, P., Chevalier, Py., Fisher, E., Mason, P., and Mignanelli, M., J. de Physique IV-France, 2004, vol. 113, p. 61.

    Article  CAS  Google Scholar 

  7. Surendran, K.P., Mohanan, P., and Sebastian, M.T., J. Solid State Chem., 2004, vol. 177, no. 11, p. 4031.

    Article  CAS  Google Scholar 

  8. Dosler, U., Krzmanc, M.M., and Suvorov, D., Abstracts of Papers, Tenth Annual Conference YUCOMAT 2008, Serbia, 2008, p. 98.

  9. Abstracts of Papers, Nattapol Laorodphan, Development of Glass-Ceramics as Seals in Planar Solid Oxide Fuel Cells, Thailand, Chiang Mai University, 2009, p. 4.

  10. Pavlushkin, N.M., Osnova tekhnologii stekla (Foundations of Glass Technology), Moscow: Ross. Khim. Gos. Univ. im. D.I.Mendeleeva, 1977.

    Google Scholar 

  11. Diagrammy sostoyaniya silikatnykh system (Phase Diagrams of Silicate Systems), Toropov, N.A., Barzakovskii, V.P., Kurtseva, N.N., Boikova, A.I., and Lapina, V.V., Eds., Leningrad: Nauka, 1972.

    Google Scholar 

  12. Kuzel, H.-J., Neues Jahrb. Mineral., Abhandl., 1963, vol. 100, no. 3, p. 322.

    CAS  Google Scholar 

  13. Stolyarova, V.L., Lopatin, S.I., Shugurov, S.M., and Shilov, A.L., Zh. Obshch. Khim., 2010, vol. 80, no. 4, p. 529.

    Google Scholar 

  14. Kambayashi, S. and Kato, E., J. Chem. Thermodyn., 1983, vol. 15, no. 7, p. 701.

    Article  CAS  Google Scholar 

  15. Kambayashi, S. and Kato, E., J. Chem. Thermodyn., 1984, vol. 16, no. 3, p. 241.

    Article  CAS  Google Scholar 

  16. Stolyarova, V.L., Lopatin, S.I., and Bondar’, V.V., Dokl. Akad. Nauk, 2004, vol. 399, no. 1, p. 82.

    Google Scholar 

  17. Stolyarova, V.L., Lopatin S.I., and Bondar’, V.V., Khim. Tekhnol., 2004, no. 11, p. 14.

  18. Shul’ts, M.M., Ivanov, G.G., Stolyarova, V.L., and Shakhmatkin, B.A., Fiz. Khim. Stekla, 1986, vol. 12, no. 3, p. 285.

    Google Scholar 

  19. Boike, M., Hilpert, K., and Muller, F., J. Am. Ceram. Soc., 1993, vol. 76, no. 11, p. 2809.

    Article  CAS  Google Scholar 

  20. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu: Spravochnik (Energies of Breaking Chemical Bonds: Ionization Potentials and Electron Affinities: Handbook), Kondrat’ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

  21. Belton, G.R. and Fruechan, R.J., Mettallurg. Trans., 1970, vol. 1, no. 4, p. 781.

    CAS  Google Scholar 

  22. Stolyarova, V.L., Lopatin, S.I., and Shugurov, S.M., Zh. Obshch. Khim., 2008, vol. 78, no. 10, p. 1639.

    Google Scholar 

  23. Bondar’, V.V., Lopatin, S.I., and Stolyarova, V.L., Neorg. Mater., 2005, vol. 41, no. 4, p. 434.

    Article  Google Scholar 

  24. Termodinamicheskie svoistva individual’nykh veshchestv: Spravochnic (Thermodynamic Properties of Pure Substances: Handbook), Glushko, V.P., Ed., Moscow: Akad. Nauk SSSR, 1978–1984, vols. 1–4.

    Google Scholar 

  25. Paule, R.C. and Mandel, J., Pure Appl. Chem., 1972, vol. 31, no. 3, p. 371.

    Article  Google Scholar 

  26. Mann, J.B., J. Chem. Phys., 1967, vol. 46, no. 5, p. 1646.

    Article  CAS  Google Scholar 

  27. Guido, M. and Gigli, G., High Temp. Sci., 1975, vol. 7, no. 2, p. 122.

    CAS  Google Scholar 

  28. Stolyarova, V.L., Archakov, I.Yu., and Shultz, M.M., High Temp. Sci., 1990, vol. 28, no. 1, p. 79.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    V. L. Stolyarova, S. I. Lopatin, S. M. Shugurov & A. L. Shilov

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  1. V. L. Stolyarova
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  2. S. I. Lopatin
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  3. S. M. Shugurov
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  4. A. L. Shilov
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Corresponding author

Correspondence to V. L. Stolyarova.

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Original Russian Text © V.L. Stolyarova, S.I. Lopatin, S.M. Shugurov, A.L. Shilov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 12, pp. 1943–1951.

1 For communication VI, see [1].

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Stolyarova, V.L., Lopatin, S.I., Shugurov, S.M. et al. Thermodynamic properties of silicate glasses and melts: VII. System MgO-B2O3-SiO2 . Russ J Gen Chem 80, 2405–2413 (2010). https://doi.org/10.1134/S1070363210120029

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  • DOI: https://doi.org/10.1134/S1070363210120029

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