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Complexing ability of the substituted oxathiacrown ethers with vicinal arrangement of the sulfur atoms

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Abstract

Complexing ability of crown ethers opens new ways of designing selective extragents and sensitive receptors to various metal cations. The structure of the oxathiacrown ether complexes with Ag(I), Pb(II), Hg(II), Cd(II), Ni(II), Pd(II) ions was investigated using the methods of mass spectrometry and 1H NMR spectroscopy. Formation of 1:1 and 2:1 ligand-metal complexes was established.

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References

  1. Izatt, R.M., Bradshaw, J.S., Nielsen, S.A., Lamb, J.D., Christensen, J.J., and Sen, D., Chem. Rev., 1985, vol. 85, p. 271.

    Article  CAS  Google Scholar 

  2. Izatt, R.M., Pawlak, K., Bradshaw, J.S., and Bruening, R.L., Chem. Rev., 1991, vol. 91, p. 1721.

    Article  CAS  Google Scholar 

  3. Izatt, R.M., Pawlak, K., Bradshaw, J.S., and Bruening, R.L., Chem. Rev., 1995, vol. 95, p. 2529.

    Article  CAS  Google Scholar 

  4. Sibert, W., Lange, S.J., Hoffman, B.M., Williams, D.J., and Barrett, A.G.M., Inorg. Chem., 1995, vol. 34, p. 2300.

    Article  CAS  Google Scholar 

  5. Drexler, H.-J., Grotjahn, M., Kleinpeter, E., and Holdt, H.-J., Inorg. Chim. Acta., 1999, vol. 285, p. 305.

    Article  CAS  Google Scholar 

  6. Karaboecek, S., Degirmencioglu, I., Karaboecek, N., and Serbest, K., Transition Met. Chem., 2003, vol. 28, p. 529.

    Article  CAS  Google Scholar 

  7. One, M., Akama, K., Kimura, K., Tanaka, K., and Shono, T., J. Chem. Soc., Perkin Trans., 1989, vol. 1, p. 1675.

    Google Scholar 

  8. Bradshaw, J.S., Krakowiak, K.E., Izatt, R.M., Brus, L., and Tarbet, B.J., J. Heterocycl. Chem., 1990, vol. 27, p. 347.

    Article  CAS  Google Scholar 

  9. Buter, J., Kellog, R.M., and van Bolhuis, F., J. Chem. Soc. Chem. Comm., 1991, p. 910.

  10. Lukas, C.R. and Liu, S., Inorg. Chim. Acta, 1995, vol. 230, p. 133.

    Article  Google Scholar 

  11. Drexler, H.-J., Starke, I., Grotjahn, M., Kleinpeter, E., and Holdt, H.-J., Inorg. Chim. Acta, 2001, vol. 317, p. 133.

    Article  CAS  Google Scholar 

  12. Rezekina, N.A., Rakhmanov, E.V., Lukovskaya, E.V., Bobylyova, A.A., Abramov, A.A., Chertkov, V.A., Khoroshutin, A.V., and Anisimov, A.V., Chem. Heterocycl. Comp., 2006, vol. 42, no. 2, p. 216.

    Article  CAS  Google Scholar 

  13. Rezekina, N.A., Rakhmanov, E.V., Lukovskaya, E.V., Bobylyova, A.A., Chertkov, V.A., Kostyuchenko, O.V., Abramov, A.A., and Anisimov, A.V., Vestn. Mosk. Univ. Ser. 2. Khimiya, 2006. 47, no. 3, p. 236.

    CAS  Google Scholar 

  14. Zenina, A.A., Rakhmanov, E.V., Bobyleva, A.A., Lukovskaya, E.V., Kuzmina, L.G., Abramov, A.A., and Anisimov, A.V., Chem. Heterocycl. Comp., 2007, vol. 43, no. 7, p. 835.

    Article  CAS  Google Scholar 

  15. Grant, G.J., Chen, W.N., Goforth, A.M., Baucom, C.L., Patel, K., Repovic, P., van Derveer, D.G., and Pennington, W.T., Eur. J. Inorg. Chem., 2005, no. 3, p. 479.

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Authors and Affiliations

  1. Chemical Department, Lomonosov Moscow State University, Vorob’evy Gory 1, Moscow, 119992, Russia

    E. V. Rakhmanov, A. A. Bobyleva, E. V. Lukovskaya, O. A. Fedorova & A. V. Anisimov

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  1. E. V. Rakhmanov
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  2. A. A. Bobyleva
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  3. E. V. Lukovskaya
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  4. O. A. Fedorova
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  5. A. V. Anisimov
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Correspondence to E. V. Rakhmanov.

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Original Russian Text © E.V. Rakhmanov, A.A. Bobyleva, E.V. Lukovskaya, O.A. Fedorova, A.V. Anisimov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 11, pp. 1860–1865.

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Rakhmanov, E.V., Bobyleva, A.A., Lukovskaya, E.V. et al. Complexing ability of the substituted oxathiacrown ethers with vicinal arrangement of the sulfur atoms. Russ J Gen Chem 80, 2323–2328 (2010). https://doi.org/10.1134/S1070363210110162

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  • DOI: https://doi.org/10.1134/S1070363210110162

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