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Autocatalysis in oxidation reactions of verdazyl radicals with hydroperoxides

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Abstract

The reaction of 2,4,6-triphenyl- and 2,3,4,6-tetraphenylverdazyl with tert-butyl hydroperoxide in acetonitrile solution and acetonitrile-water mixture was studied. This reaction was shown to be autocatalytic owing to verdazylium hydroxide formation in the course of the reaction. The main kinetic parameters were determined for the catalytic and non-catalytic reactions.

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References

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Authors and Affiliations

  1. Ogarev Mordvian State University, ul. Bol’shevistskaya 68, Saransk, 430000, Russia

    V. I. Buzulukov

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  1. V. I. Buzulukov
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Correspondence to V. I. Buzulukov.

Additional information

Original Russian Text © V.I. Buzulukov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 11, pp. 1843–1845.

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Buzulukov, V.I. Autocatalysis in oxidation reactions of verdazyl radicals with hydroperoxides. Russ J Gen Chem 80, 2306–2308 (2010). https://doi.org/10.1134/S1070363210110125

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  • DOI: https://doi.org/10.1134/S1070363210110125

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