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Studies of adsorption of 2,2′-bipyridyl on the surface of highly regulated silica matrix of the MCM-41 type by means of 15N NMR spectroscopy

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Abstract

The study of 2,2′-bipyridyl adsorption on the surface of highly regular MCM-41 silica at 300 and 130 K was carried out by the 15N NMR spectroscopy. It was shown that at 300 K the adsorbed molecules were involved in the processes of isotropic reorientation accompanied by the formation and rupture of hydrogen bonds with the surface-located hydroxy groups. Each molecule of 2,2′-bipyridyl forms no more than one hydrogen bond at a time, and their surface density is about one molecule per 1 nm2 of the surface. At 130 K 2,2′-bipyridyl forms a monolayer on the surface of silica including about 1.6 molecule per 1 nm2. In this monolayer each molecule forms a hydrogen bond with one hydroxy group and prevents the interaction of the other bipyridyl molecules with one more hydroxy group.

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Authors and Affiliations

  1. St. Petersburg State University, ul. Ul’yanovskaya 3, St. Petersburg, 198504, Russia

    S. B. Lesnichin, G. S. Denisov & I. G. Shenderovich

  2. Institute of Chemistry and Biochemistry of the Berlin Free University, Berlin, Germany

    S. B. Lesnichin, N. Kamdem, D. Mauder & I. G. Shenderovich

Authors
  1. S. B. Lesnichin
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  2. N. Kamdem
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  3. D. Mauder
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  4. G. S. Denisov
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  5. I. G. Shenderovich
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Correspondence to I. G. Shenderovich.

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Original Russian Text © S.B. Lesnichin, N. Kamdem, D. Mauder, G.S. Denisov, I.G. Shenderovich, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 10, pp. 1718–1722.

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Lesnichin, S.B., Kamdem, N., Mauder, D. et al. Studies of adsorption of 2,2′-bipyridyl on the surface of highly regulated silica matrix of the MCM-41 type by means of 15N NMR spectroscopy. Russ J Gen Chem 80, 2027–2031 (2010). https://doi.org/10.1134/S1070363210100233

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  • DOI: https://doi.org/10.1134/S1070363210100233

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