Abstract
2-Ferrocenylpropan-2-ol was synthesized by addition of ferrocene to acetone in the two-phase system petroleum ether-water using H2SO4-DEANaph as catalyst. Study on the kinetic parameters of the process showed that during the first two hours (conversion 87%) the reaction is of first order in ferrocene. The energy of activation of the addition of ferrocene to acetone under conditions of phase-transfer catalysis was estimated at 21 kcal mol−1.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Perevalova, E.G. and Reshetova, M.D., Metody elementoorganicheskoi khimii zhelezoorganicheskikh soedinenii ferrotsena (Methods of Organometallic Chemistry of Organoiron Ferrocene Compounds), Moscow: Nauka, 1983.
Temirov, S.A., Sachivko, A.V., Tverdokhlebov, V.P., and Tselinskii, I.V., Zh. Org. Khim., 1988, vol. 24, no. 11, p. 2265.
Dem’yanenko, E.A., Tverdokhlebov, V.P., Karibov, A.K., Sachivko, A.V., Verkhusha, V.I., Seredyuk, F.S., and Yaskin, V.P., Russian Patent no. 2 061 736, 1996.
Misterkiewicz, B., Dabard, R., and Patin, H., Tetrahedron, 1985, vol. 41, no. 9, p. 1685.
Bruce, M.I., Gordon, F., Stone, A, and Thomson, B.J., J. Organomet. Chem., 1974, vol. 77, p. 77.
Sokolov, V.I. and Suleimanov, G.Z., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, no. 7, p. 1647.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Z.G. Kurbanov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 7, pp. 1122–1124.
Rights and permissions
About this article
Cite this article
Kurbanov, Z.G. Synthesis 2-ferrocenylpropan-2-ol under conditions of phase-transfer catalysis and kinetic relations holding in this reaction. Russ J Gen Chem 80, 1288–1290 (2010). https://doi.org/10.1134/S1070363210070121
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363210070121