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Kinetics of the reaction of sodium arsenite with bromo- and iodoacetic acids

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Abstract

By an example of the reaction of sodium arsenite with bromoacetic and iodoacetic acids the effect of halogen on the rate of Meyer reaction was evaluated. Rate constants and the activation energy and entropy values were estimated. Effects of the nature of halogen and temperature on the ratio of rate constants of the Meyer reaction and the competing alkaline hydrolysis of haloacetic acids were evaluated.

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Authors and Affiliations

  1. Kazan State Technological University, ul. K. Marksa 68, Kazan, 420015, Tatarstan, Russia

    R. R. Rakhmatullin & V. I. Gavrilov

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  1. R. R. Rakhmatullin
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  2. V. I. Gavrilov
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Correspondence to R. R. Rakhmatullin.

Additional information

Original Russian Text © R.R. Rakhmatullin, V.I. Gavrilov, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 7, pp. 1106–1109.

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Rakhmatullin, R.R., Gavrilov, V.I. Kinetics of the reaction of sodium arsenite with bromo- and iodoacetic acids. Russ J Gen Chem 80, 1272–1275 (2010). https://doi.org/10.1134/S1070363210070091

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  • DOI: https://doi.org/10.1134/S1070363210070091

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