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Reaction of unsaturated nitriles with hydrosilanes

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Abstract

Reaction of acrylonitrile and 1,4-dicyanobut-1-ene with hydrosilanes in the presence of various catalysts was studied. In the presence of triallylamine, allyl-bis(triethoxypropyl)amine, diallylaminopropyltriethoxysilane, HMPA, NiCl2 + 2MePh2PO, CuCl + 2MePh2PO, [(Me2N)2CCl]2CuCl4, and [(Me2N)2CCl]2PtCl6, the addition of trichlorosilane to acrylonitrile proceeded with the yield of 36 to 97%. Triethoxy- and tributoxysilane were added to acrylonitrile in the presence of rhodium dicarbonyl acetylacetonate with the formation of α-isomer in 56–58% yield. Attempted addition of hydrosilanes to 1,4-dicyanobutene failed.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelemental Compounds, sh. Entuziastov 38, Moscow, 111123, Russia

    Z. V. Belyakova, M. G. Pomerantseva, E. N. Chekrii, E. A. Chernyshev & P. A. Storozhenko

Authors
  1. Z. V. Belyakova
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  2. M. G. Pomerantseva
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  3. E. N. Chekrii
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  4. E. A. Chernyshev
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  5. P. A. Storozhenko
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Corresponding author

Correspondence to Z. V. Belyakova.

Additional information

Original Russian Text © Z.V. Belyakova, M.G. Pomerantseva, E.N. Chekrii, E.A. Chernyshev, P.A. Storozhenko, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 5, pp. 757–759.

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Belyakova, Z.V., Pomerantseva, M.G., Chekrii, E.N. et al. Reaction of unsaturated nitriles with hydrosilanes. Russ J Gen Chem 80, 927–929 (2010). https://doi.org/10.1134/S1070363210050105

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  • DOI: https://doi.org/10.1134/S1070363210050105

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