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Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds

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Abstract

The reaction of heterobidentate 4-(dimethylamino)phenyldiphenylphosphine with labile cluster Rh6(CO)15(NCMe) yielding a new monosubstituted cluster Rh6(CO)15(Ph2PC6H4NMe2) was described. The reactions of the resulting cluster with GaX3 compounds were studied. The structure of all obtained compounds was completely characterized both in a solid phase and in a solution by X-ray diffraction analysis, mass spectrometry, and IR and polynuclear NMR spectroscopy.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    E. V. Gracheva

  2. Heidelberg University, Heidelberg, Germany

    G. Linti

Authors
  1. E. V. Gracheva
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  2. G. Linti
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Correspondence to E. V. Gracheva.

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Original Russian Text © E.V. Gracheva, G. Linti, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 3, pp. 389–397.

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Gracheva, E.V., Linti, G. Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO)15[(C6H5)2PC6H4N(CH3)2] and {Rh6(CO)15[(C6H5)2PC6H4NH(CH3)2]}[GaX4] cluster compounds. Russ J Gen Chem 80, 414–422 (2010). https://doi.org/10.1134/S1070363210030072

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  • DOI: https://doi.org/10.1134/S1070363210030072

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