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Binuclear and polynuclear complexes of Schiff bases

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Abstract

The data on the synthesis of binuclear and polynuclear homo- and heterometallic complexes of aromatic and heterocyclic (azole) Schiff bases are summarized and systematized. Influence is revealed of the structure (nature of aldehyde and amine moieties and intermetallic bridges) of azomethine binuclear copper chelates on their magnetic characteristics. The complexes with N,N-or S,S-bridging atoms are shown to lead, in general, to ferromagnetic exchange whereas O,O-intermetal binding leads to antiferromagnetic spin-spin coupling.

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  1. Southern Federal University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    A. D. Garnovskii, I. S. Vasil’chenko, A. S. Burlov & A. I. Uraev

  2. Southern Scientific Center Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii

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Original Russian Text © A.D. Garnovskii, I.S. Vasil’chenko, D.A. Garnovskii, A.S. Burlov, A.I. Uraev, 2009, published in Rossiiskii Khimicheskii Zhurnal, 2010, Vol. 53, No. 1, pp. 100–109.

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Garnovskii, A.D., Vasil’chenko, I.S., Garnovskii, D.A. et al. Binuclear and polynuclear complexes of Schiff bases. Russ J Gen Chem 79, 2776–2786 (2009). https://doi.org/10.1134/S1070363209120366

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  • DOI: https://doi.org/10.1134/S1070363209120366

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