Skip to main content
SpringerLink
Log in

Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Basic structural principles of uranyl selenates with organic templates are outlined as follows. In compounds with short chain amine molecules (C:N < 8) the primary role plays the correspondence between topology of inorganic complex (isomerism) and structure and shape of a template. In the structures with long chain molecules (C:N ≤ 8), the molecules are associated to form 2- or 1-dimensional supramolecular templates that are connected with inorganic structure according to the charge density matching principle. Compounds with electro neutral molecules (crown ethers) have composite structure, where bonding between organic and inorganic parts is achieved through hydrogen bonding via intermediate oxonium clusters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Structural Chemistry of Inorganic Actinide Compounds, Krivovichev, S.V., Burns, P.C., and Tananaev, I.G., Eds., Amsterdam: Elsevier, 2007.

    Google Scholar 

  2. Burns, P.C., Hughes Kubatko, K.-A., Sigmon, G., Fryer, B.J., Gagnon, J.E., Antonio, M.R., and Soderholm, L., Angew. Chem. Int. Ed., 2005, vol. 44, pp. 2135–2137.

    Article  CAS  Google Scholar 

  3. Krivovichev, S.V., Kahlenberg, V., Kaindl, R., Mersdorf, E., Tananaev, I.G., and Myasoedov, B.F., Angew. Chem. Int. Ed., 2005, vol. 44, pp. 1134–1136.

    Article  CAS  Google Scholar 

  4. Krivovichev, S.V., Kahlenberg, V., Kaindl, R., Mersdorf, E., Tananaev, I.G., and Myasoedov, B.F., J. Am. Chem. Soc., 2005, vol. 127, pp. 1072–1073.

    Article  CAS  Google Scholar 

  5. Krivovichev, S.V., Tananaev, I.G., Kalenberg, V., Kaindl’, R., and Myasoedov, B.F., Radiokhimiya, 2005, vol. 47, pp. 481–491.

    Google Scholar 

  6. Krivovichev, S.V. and Tananaev, I.G., Ros. Khim. Zh. (Zh. Ros. Khim. Ob-va im. D.I. Mendeleeva), 2005, vol. 49, no. 2, pp. 115–118.

    CAS  Google Scholar 

  7. Krivovichev, S.V., Burns, P.C., Tananaev, I.G., and Myasoedov, B.F., J. Alloys Comp., 2007, vols. 444–445, pp. 457–463.

    Article  Google Scholar 

  8. Baggio, R.F., de Benyacar, M.A.R., Perazzo, B.O., and de Perazzo, P.K., Acta Cryst. Part B, 1977, vol. 33, pp. 3495–3499.

    Article  Google Scholar 

  9. Mikhailov, Yu.N., Gorbunova, Yu.E., Demchenko, E.A., Serezhkina, L.B., and Serezhkin, V.N., Zh. Neorg. Khim., 2000, vol. 45, pp. 1711–1713.

    CAS  Google Scholar 

  10. Doran, M.B., Norquist, A.J., and O’Hare, D., Inorg. Chem., 2003, vol. 42, pp. 6989–6994.

    Article  CAS  Google Scholar 

  11. Doran, M.B., Norquist, A.J., Stuart, C.L., and O’Hare, D., Acta Crystallogr., Part E, 2004, vol. 60, pp. m996–m998.

    Article  Google Scholar 

  12. Doran, M.B., Cockbain, B.E., and O’Hare, D., Dalton Trans., 2005, vol. 2005, pp. 1774–1780.

    Article  Google Scholar 

  13. Almond, P.M. and Albrecht-Schmitt, T.E., Inorg. Chem., 2003, vol. 42, pp. 5693–5698.

    Article  CAS  Google Scholar 

  14. Halasyamani, P.S., Francis, R.J., Walker, S.M., and O’Hare, D., Inorg. Chem., 1999, vol. 38, pp. 271–279.

    Article  CAS  Google Scholar 

  15. Norquist, A.J., Thomas, P.M., Doran, M.B., and O’Hare, D., Chem. Mater., 2002, vol. 14, pp. 5179–5184.

    Article  CAS  Google Scholar 

  16. Norquist, A.J., Doran, M.B., Thomas, P.M., and O’Hare, D., Dalton Trans., 2003, vol. 23, pp. 1168–1175.

    Article  Google Scholar 

  17. Norquist, A.J., Doran, M.B., Thomas, P.M., and O’Hare, D., Inorg. Chem., 2003, vol. 42, pp. 5949–5953.

    Article  CAS  Google Scholar 

  18. Norquist, A.J., Doran, M.B., and O’Hare, D., Solid State Sci., 2003, vol. 5, pp. 1149–1158.

    Article  CAS  Google Scholar 

  19. Norquist, A.J., Doran, M.B., and O’Hare, D., Inorg. Chem., 2005, vol. 44, pp. 3837–3843.

    Article  CAS  Google Scholar 

  20. Krivovichev, S.V., Tananaev, I.G., Kalenberg, V., and Myasoedov, B.F., Dokl. Russ. Akad. Nauk, 2005, vol. 403, pp. 349–352.

    Google Scholar 

  21. Krivovichev, S.V., Kahlenberg, V., Tananaev, I.G., and Myasoedov, B.F., Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 2358–2364.

    Article  CAS  Google Scholar 

  22. Krivovichev, S.V. and Kahlenberg, V., Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 2352–2357.

    Article  CAS  Google Scholar 

  23. Krivovichev, S.V., Kahlenberg, V., Kaindl, R., and Mersdorf, E., Eur. J. Inorg. Chem., 2005, vol. 2005, pp. 1653–1656.

    Article  Google Scholar 

  24. Krivovichev, S.V., Gurzhii, V.V., Tananaev, I.G., and Myasoedov, B.F., Dokl. Russ. Akad. Nauk, 2006, vol. 409, pp. 625–629.

    Google Scholar 

  25. Krivovichev, S.V., Tananaev, I.G., Kalenberg, V., and Myasoedov, B.F., Radiokhimiya, 2006, vol. 48, pp. 197–201.

    Google Scholar 

  26. Krivovichev, S.V., Tananaev, I.G., and Myasoedov, B.F., Radiokhimiya, 2006, vol. 48, pp. 481–488.

    Google Scholar 

  27. Krivovichev, S.V., Tananaev, I.G., and Myasoedov, B.F., C. R. Chimie, 2007, vol. 10, pp. 897–904.

    CAS  Google Scholar 

  28. Krivovichev, S.V., Gurzhii, V.V., Tananaev, I.G., and Myasoedov, B.F., Zapp. Ros. Mineral. Ob-va, 2007, special issue, no. 7, pp. 91–114.

  29. Forbes, T.Z., McAlpin, J.G., Murphy, R., and Burns, P.C., Angew. Chem. Int. Ed., 2008, vol. 47, pp. 2824–2827.

    Article  CAS  Google Scholar 

  30. Krivovichev, S.V., Crystallogr. Rev., 2004, vol. 10, pp. 185–232.

    Article  CAS  Google Scholar 

  31. Krivovichev, S.V., Structural Crystallography of Inorganic Oxysalts, Oxford: Oxford University Press, 2009.

    Book  Google Scholar 

  32. Krivovichev, S.V., Gurzhiy, V.V., Tananaev, I.G., and Myasoedov, B.F., Z. Kristallogr., 2009, vol. 224, pp. 316–324.

    Article  CAS  Google Scholar 

  33. Moore, P.B., N. Jb. Miner. Mh., 1970, vol. 1970, pp. 163–173.

    Google Scholar 

  34. Hawthorne, F.C., Acta Cryst., Part A, 1983, vol. 39, pp. 724–736.

    Article  Google Scholar 

  35. Krivovichev, S.V., N. Jb. Mineral. Mh., 2004, vol. 24, pp. 209–220.

    Article  Google Scholar 

  36. Krivovichev, S.V., Cahill, C.L., and Burns, P.C., Inorg. Chem., 2002, vol. 41, pp. 34–39.

    Article  CAS  Google Scholar 

  37. Krivovichev, S.V., Kahlenberg, V., Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 739–744.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    S. V. Krivovichev & V. V. Gurzhiy

  2. Institute of Geochemistry and Analytical Chemistry, ul. Kosygina 19, Moscow, 119991, Russia

    I. G. Tananaev & B. F. Myasoedov

Authors
  1. S. V. Krivovichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Gurzhiy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. G. Tananaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. F. Myasoedov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. F. Myasoedov.

Additional information

Original Russian Text © S.V. Krivovichev, V.V. Gurzhiy, I.G. Tananaev, B.F. Myasoedov, 2009, published in Rossiiskii Khimicheskii Zhurnal, 2010, Vol. 53, No. 1, pp. 16–22.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krivovichev, S.V., Gurzhiy, V.V., Tananaev, I.G. et al. Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization. Russ J Gen Chem 79, 2723–2730 (2009). https://doi.org/10.1134/S1070363209120317

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363209120317

Keywords

Search

Navigation