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Coordination supramolecular structures

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Abstract

Supramolecular coordination ensembles with d-metal ions directly incorporated into their structures are the subject of the present review. Diversity of such structures considerably exceeds that of purely organic supramolecules due to inclusion of additional polyvalent metal atoms (totally sixty) with diverse coordination geometry. Such metal-containing constructions are generated by self-assembling and (or) by templating, as 2D and 3D geometric figures (polygons and polyhedra) and “furniture” constructions (ladders, racks, grids) together with helicates, interwoven species and metallodendrimers as combinations of 1D coordination compounds. Besides, is presented a numerous of coordination polymers and supramolecular crystal lattices as infinite structures.

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  1. Southern Federal University, prosp. Stachki, 194/2, Rostov-on-Don, 344090, Russia

    Yu. E. Alekseev & A. D. Garnovskii

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Original Russian Text © Yu.E. Alekseev, A.D. Garnovskii, 2009, published in Rossiiskii Khimicheskii Zhurnal, 2009, Vol. 53, No. 1, pp. 6–15.

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Alekseev, Y.E., Garnovskii, A.D. Coordination supramolecular structures. Russ J Gen Chem 79, 2711–2722 (2009). https://doi.org/10.1134/S1070363209120305

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