Abstract
Hydrosilylation of allyl esters of fluoro acids and ethers of fluoro alcohols with hydrochlorosilanes in the presence of the Speier’s catalyst was studied. Yields of adducts with ethers reach 62–68%, and with esters, 27–45%. By etherification of the adduts with ethers the respective ethoxysilanes were obtained in 41–43% yield. The latter reaction even in very mild conditions is complicated by the formation of a large amount of siloxanes. Yield of siloxanes is 22–32%.
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Original Russian Text © Z.V. Belyakova, M.G. Pomerantseva, E.A. Chernyshev, P.A. Storozhenko, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 12, pp. 2008–2010.
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Belyakova, Z.V., Pomerantseva, M.G., Chernyshev, E.A. et al. Hydrosilylation of unsaturated fluorinated esters and ethers with hydrochlorosilanes. Russ J Gen Chem 79, 2634–2636 (2009). https://doi.org/10.1134/S1070363209120123
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DOI: https://doi.org/10.1134/S1070363209120123