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Reaction of diethyl 3-methyl-1,2-butadienylphosphonate with 1,10-diaza-18-crown-6

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Abstract

Reaction of two-fold excess of diethyl 3-methyl-1,2-butadienylphosphonate with 1,10-diaza-18-crown-6 leads to the formation of an adduct whose molecule includes two 1-phosphoryl-3-methyl-2-butene fragments bound together by a crown bridge with the anti location of organophosphorus groups relative to the macrocycle plane. The 1,2-multiple bond of the phosphonate is involved in the reaction. Extraction properties of the diphosphorylated crown ether toward alkali metal picrates were studied.

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Authors and Affiliations

  1. Butlerov Chemical Institute, Kazan State University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia

    N. G. Khusainova, S. M. Rybakov, D. A. Safin & R. A. Cherkasov

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    D. B. Krivolapov & B. A. Litvinov

Authors
  1. N. G. Khusainova
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  2. S. M. Rybakov
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  3. D. A. Safin
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  4. D. B. Krivolapov
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  5. B. A. Litvinov
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  6. R. A. Cherkasov
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Correspondence to N. G. Khusainova.

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Original Russian Text © N.G. Khusainova, S.M. Rybakov, D.A. Safin, D.B. Krivolapov, B.A. Litvinov, R.A. Cherkasov, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 12, pp. 1999–2002.

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Khusainova, N.G., Rybakov, S.M., Safin, D.A. et al. Reaction of diethyl 3-methyl-1,2-butadienylphosphonate with 1,10-diaza-18-crown-6. Russ J Gen Chem 79, 2625–2628 (2009). https://doi.org/10.1134/S107036320912010X

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  • DOI: https://doi.org/10.1134/S107036320912010X

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