Abstract
Initiated oxidation of cumene with oxygen in the presence of various phenol antioxidants and a supramolecular system containing the oxygen radical anion of was studied. It is shown that superoxide anion and ionol, hydroquinone, and ethyl gallate are the antagonists in the process of inhibition of the radical chain oxidation. Simultaneous introduction of the ascorbic acid and the radical anion of oxygen caused the synergistic effect.
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Tselinskii, I.V., Shugaley, I.V., and Lukogorskaya, S.A., Ross. Khim. Zh., 2001, vol. 45, no. 2, p. 35.
Matsumoto, S., Sugimoto, H., and Sawyer, D.T., Chem. Res. Toxicol., 1998, vol. 1, p. 10.
Gogotov, A.F., Zav’yalova, A.A., and Levchuk, A.A., Khimiya rastitel’nogo syr’ya, 2006, no. 3, p. 49.
Denisov, E.T., Usp. Khim., 1996, vol. 65, no. 5, p. 547.
Denisov, E.T., Kinetika i Kataliz, 1998, vol. 65, no. 6, p. 547.
Frimer Aryeh, A., Farkash-Solomon, T., and Aljadeff, G., J. Org. Chem., 1986, vol. 51, no. 11, p. 2093.
Afanas’ev, I.B., Kupriyanova, N.S., and Grabovetskii, V.V., Zh. Obshch. Khim., 1986, vol. 56, no. 6, p. 1326.
Opeida, I.A. and Kucher, R.V., Ukr. Khim. Zh., 1997, vol. 36, p. 1040.
Opeida, I.A., Efimova, I.V., and Kachurin, I.O., Teor. Eksper. Khim., 1997, vol. 33, no. 4, p. 229.
Efimova, I.V., Pomeshchenko, A.I., and Opeida, I.O., Zh. Obshch. Khim., 2004, vol. 74, no. 7, p. 1100.
Opeida, I.A., Pomeshchenko, A.I., and Efimova, I.V., Zh. Fiz. Khim., 2004, vol. 78, no. 11, p. 1976.
Nunez-Delicado, E., Sanchez-Ferrer, A., and Garcia-Carmona, F., J. Agric. Food Chem., 1997, vol. 45, p. 2830.
Borisenkova, S.A., Girenko, E.G., and Kaliya, O.L., Ross. Khim. Zh., 1998, vol. 42, no. 5, p. 111.
Frimer, A.A., Marks, V., and Gilinsky, P.S., J. Org. Chem., 1995, vol. 60, p. 4510.
Emmanuel’, N.M., Zaikov, G.E., and Maizus, Z.K., Rol’ sredy v radikal’no-tsepnykh reaktsiyakh organicheskikh soedinenii (Role of the Medium in the Oxidation Reactions of the Organic Compounds), Moscow: Nauka, 1973.
Wilfred, L.F., Armagero, C., and Chai, L.L., Purification of Laboratory Chemicals, 5E, Elsevier Science, 2003.
Hiraoka, M., Kraun-soedineniya. Svoistva I Primemenie (Crown Compounds. Properties and Use), Moscow: Mir, 1986.
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Original Russian Text © A.I. Pomeshchenko, O.V. Smirnova, I.V. Efimova, I.A. Opeida, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 10, pp. 1688–1691.
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Pomeshchenko, A.I., Smirnova, O.V., Efimova, I.V. et al. Joint action of antioxidants of phenol type and superoxide anion in the oxidation reactions. Russ J Gen Chem 79, 2183–2186 (2009). https://doi.org/10.1134/S1070363209100168
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DOI: https://doi.org/10.1134/S1070363209100168