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Application of aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]amine to the synthesis of linear and heterocyclic compounds

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Abstract

Reaction of 3-aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]-amine and their derivatives with diethylcarbamic acid trimethylsilyl ether and trimetisilylisocyanate proceeds through the stage of formation of intermediate products which under conditions of the synthesis undergo intramolecular (in the case of formation O-silylcarbamates) and intermolecular (in the case of the formation of carbamide trimethylsilyl derivatives) desilylation leading to the cyclic and linear products respectively.

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References

  1. Sheludyakov, V.D., Kirilin, A.D., and Mironov, V.F., Zh. Obshch. Khim., 1975, vol. 45, no. 3, p. 707.

    CAS  Google Scholar 

  2. Sheludyakov, V.D., Kirilin, A.D., Gusev, A.I., and Sharapov, V.A., Zh. Obshch. Khim., 1976, vol. 46, no. 12, p. 2712.

    CAS  Google Scholar 

  3. Ziche, W., Zeimer, B., John, P., Weis, J., and Auner, N., J. Organomet. Chem., 1996, vol. 521, p. 29.

    Article  CAS  Google Scholar 

  4. Jal, P.K., Patel, S., and Mishra, B.K., Talanta, 2004, vol. 62, p. 1005.

    Article  CAS  Google Scholar 

  5. Goubert-Renaudin, S., Schneider, R., and Walcarius, A., Tetrahedron Lett., 2007, vol. 48, p. 2113.

    Article  CAS  Google Scholar 

  6. Grotenhuis, T.A., USA Patent no. 3249461, 1966.

  7. Kozyukov, V.P., Sheludyakov, V.D., and Mironov, V.F., Usp. Khim., 1973, vol. 42, no. 8, p. 1451.

    CAS  Google Scholar 

  8. Kirilin, A.D., Belova, L.O., Knyazev, S.P., Lega, A.V., Petrov, M.Yu., and Chernyshev, E.A., Zh. Obshch. Khim., 2005, vol. 75, no. 12, p. 1227.

    Google Scholar 

  9. Kozyukov, V.P., Sheludyakov, V.D., and Mironov, V.F., Usp. Khim., 1975, vol. 44, no. 5, p. 897.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Lomonosov Moscow State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    A. D. Kirilin, L. O. Belova, A. V. Gavrilova & E. A. Korobova

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  1. A. D. Kirilin
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  2. L. O. Belova
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  3. A. V. Gavrilova
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  4. E. A. Korobova
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Corresponding author

Correspondence to A. D. Kirilin.

Additional information

Original Russian Text © A.D. Kirilin, L.O. Belova, A.V. Gavrilova, E.A. Korobova, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 10, pp. 1642–1646.

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Kirilin, A.D., Belova, L.O., Gavrilova, A.V. et al. Application of aminopropyltriethoxysilane and N-[2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]amine to the synthesis of linear and heterocyclic compounds. Russ J Gen Chem 79, 2137–2141 (2009). https://doi.org/10.1134/S1070363209100119

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  • DOI: https://doi.org/10.1134/S1070363209100119

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