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Crystalline and molecular design of functionalized viologens

Russian Journal of General Chemistry volume 79, Article number: 1910 (2009) Cite this article

Abstract

The regularities of molecular and crystalline structure of functionalized (including mesoionic) viologens were systematically studied. For this purpose a number of fundamentally new viologenic systems was synthesized containing functional groups in side substituents. As a result of extensive X-ray structural studies it is revealed that unlike “classical” viologens, which in crystal form cation-anion pairs or cation-anion stacks, functionalized viologens are bound into endless chains by means of strong intermolecular hydrogen bonds.

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Authors and Affiliations

  1. Institute of Organic Chemistry of Ukraine National Academy of Sciences, ul. Murmanskaya 5, Kiev, 02660, Ukraine

    A. V. Gutov, E. B. Rusanov, A. B. Ryabitskii, I. F. Tsimbal & A. N. Chernega

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  1. A. V. Gutov
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  2. E. B. Rusanov
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  3. A. B. Ryabitskii
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  4. I. F. Tsimbal
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  5. A. N. Chernega
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Correspondence to A. V. Gutov.

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Original Russian Text © A.V. Gutov, E.B. Rusanov, A.B. Ryabitskii, I.F. Tsimbal, A.N. Chernega, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 9, pp. 1553–1561.

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Gutov, A.V., Rusanov, E.B., Ryabitskii, A.B. et al. Crystalline and molecular design of functionalized viologens. Russ J Gen Chem 79, 1910 (2009). https://doi.org/10.1134/S1070363209090175

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  • DOI: https://doi.org/10.1134/S1070363209090175

Keywords

  • General Chemistry
  • Torsion Angle
  • Bipyridine
  • Pyridine Ring
  • Carboxy Group