Skip to main content
SpringerLink
Log in

Formation of CuI(CH3CN)4ClO4 in the reactions of copper(II) perchlorate with acetonitrile in the presence of sulfur-containing organic compounds

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Cu(ClO4)2·6H2O was shown to react with 2,2′-[propane-1,3-diylbis(thio-2-phenylnemethylidene]-bis(3-pyridylamine) (I) or (5Z)-2-ethoxycarbonylmethyl-(2-pyridylmethylidene)-3,5-dihydro-4H-imidazol-4-one (II) in the presence of CH3CN with the reduction of copper(II) to copper(I) and the formation of the tetrahedral complex CuI(CH3CN)4ClO4 (III). In the course of the reaction the organic ligands I and II were oxidized to the corresponding sulfoxides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Schilstra, M.J., Birker, W.L., Verschoor, G.C., and Reedijk, J., Inorg. Chem., 1982, vol. 21, p. 2637.

    Article  CAS  Google Scholar 

  2. Olmstead, M.M., Musker, W.K., Kessler, R.M., Inorg.Chem., 1981, vol. 20, p.151.

    Article  CAS  Google Scholar 

  3. Birker, W.L., Helder, J., Henkel, G., Krebs, B., and Reedijk, J., Inorg. Chem., 1982, vol. 21, p. 357.

    Article  CAS  Google Scholar 

  4. Nanda, K.K., Addison, A.W., Butcher, R.J., McDevitt, M.R., Rao, T.N., and Sinn, E., Inorg. Chem., 1997, vol. 36, p. 134.

    Article  CAS  Google Scholar 

  5. Malachowski, M.M., Adams, M., Elia, N., Rheingold, A.L., and Kelly, R.S., J. Chem. Soc, Dalton Trans., 1999, p. 2177.

  6. Benzekri, A., Cartier, C., Latour, J.-M., Limosin, D., Rey, P., and Verdaguer, M., Inorg. Chim. Acta, 1996, vol. 252, p. 413.

    Article  CAS  Google Scholar 

  7. Nickless, D.E., Powers, M.J., and Urbach, F.L., Inorg. Chem., 1983, vol. 22, p. 3210.

    Article  Google Scholar 

  8. Latour, J.M., Limosin, D., and Rey, P., J. Chem. Soc, Chem. Commun., 1985, p. 464.

  9. Verheijdt, P.I., Hassnoot, J.G., and Reedijk, J., Inorg. Chim. Acta, 1983, vol. 76, p. L43.

    Article  CAS  Google Scholar 

  10. Mandal, S.K., Woon, T.C., Tompson, L.K., Newlands, M.J., and Gage, E.J., Aust. J. Chem., 1986, vol. 39, p. 1007.

    CAS  Google Scholar 

  11. Kitawara, U.S., Munakata, M., and Higashi, A., Inorg. Chim. Acta, 1984, vol. 84, p. 79.

    Article  Google Scholar 

  12. Sakurai, T., Kimura, M., and Nakahara, A., Bull. Chem. Soc. Jpn, 1981, vol. 54, p. 2976.

    Article  CAS  Google Scholar 

  13. Musker, W.K., Acc. Chem. Res., 1980, vol. 13, p. 1040.

    Article  Google Scholar 

  14. Colman, P.M., Freeman, H.C., Guss, J.M., Murata, M., Norris, V.A., Ramshaw, J.A.M., and Venkatappa, M.P., Nature, 1978, vol. 272, p. 319.

    Article  CAS  Google Scholar 

  15. Adman, E.T., Stenkamp, R.E., Sieker, L.C., and Jensen, L.H., J. Mol. Biol., 1978, vol. 123, p. 35.

    Article  CAS  Google Scholar 

  16. Latour, J.M., Bull. Soc. Chim. France, 1988, p. 508.

  17. Sorrell, T.N. and Cheesman, E.H., Synth. Commun., 1981, vol. 11, p. 909.

    Article  CAS  Google Scholar 

  18. Hemmerich, P. and Sigwart, G., Experientia, 1963, vol. 12, p. 488.

    Article  Google Scholar 

  19. Soregh, C., Kierkegaard, P., and Norrestam, R., Acta Cryst., Sect. B., 1975, vol. 31, p. 314.

    Article  Google Scholar 

  20. Bowmaker, G.A., Gill, D.S., Skelton, B.W., Somers, N., and White, A.H., Z. Naturforsh, B: Chem., 2004, vol. 59, p. 1307.

    CAS  Google Scholar 

  21. Cotton, F. and Wilkinson, G., Sovremennaya neorganicheskaya khimiya (Modern Inorganic Chemistry), vol. 3, Moscow: Mir, 1969.

    Google Scholar 

  22. Beloglazkina, E.K., Shimorsky, A.V., Majouga, A.G., Moiseeva, A.A., and Zyk, N.V., Izv. Akad. Nauk., Ser. Khim., 2007, vol. 56, no. 11, p. 2189.

    CAS  Google Scholar 

  23. North, A.C.T., Philips, D.C., and Mathews, F.S., Acta Cryst. A, 1968, vol. 24, p. 351

    Article  Google Scholar 

  24. Farrugia, L.A., WinGX. X-Ray Crystallographic Programs for Window, University of Glasgow, Glasgow, UK, 2003.

    Google Scholar 

  25. Sheldrick, G.M., SHELX97. Program for the Solution and Refinement of Crystal Structures, University of Gottingen, Gottingen, Germany, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia

    E. K. Beloglazkina, A. V. Shimorsky, A. G. Mazhuga, O. V. Shilova, V. A. Tafeenko & N. V. Zyk

Authors
  1. E. K. Beloglazkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Shimorsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Mazhuga
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Shilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. A. Tafeenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. V. Zyk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. K. Beloglazkina.

Additional information

Dedicated to academician B.A. Trofimov on the occasion of his 70th birthday.

Original Russian Text © E. K. Beloglazkina, A.V. Shimorsky, A.G. Mazhuga, O.V. Shilova, V.A. Tafeenko, N.V. Zyk, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 7, pp. 1147–1151.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Beloglazkina, E.K., Shimorsky, A.V., Mazhuga, A.G. et al. Formation of CuI(CH3CN)4ClO4 in the reactions of copper(II) perchlorate with acetonitrile in the presence of sulfur-containing organic compounds. Russ J Gen Chem 79, 1504–1508 (2009). https://doi.org/10.1134/S1070363209070172

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363209070172

Keywords

Search

Navigation