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Intramolecular donor-acceptor interaction in stilbene and styrene π-complexes with tricarbonylchromium. Observation in the IR spectra

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Abstract

The IR spectra of complexes derived from conjugated arylalkenes and tricarbonylchromium, namely (stilbene)tricarbonylchromium and (styrene)tricarbonylchromium, displayed three absorption bands instead of two expected in the region of carbonyl stretching vibrations (1800–2000 cm−1). Additional absorption bands also appeared in the region corresponding to metal-π-fragment stretching vibrations (250–400 cm−1). These findings indicated additional interaction involving the central metal atom, carbonyl ligands, and aromatic π-system. Such interaction increases mobility of the tricarbonylchromium fragment which may become capable of readily migrating from one π-fragment to another under certain conditions.

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Authors and Affiliations

  1. Alekseev Nizhnii Novgorod State Technical University, ul. Minina 24, Nizhnii Novgorod, 603950, Russia

    I. I. Grinval’d, A. N. Artemov, I. V. Bodrikov, L. I. Bazhan & I. Yu. Kalagaev

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  1. I. I. Grinval’d
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  2. A. N. Artemov
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  3. I. V. Bodrikov
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  4. L. I. Bazhan
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  5. I. Yu. Kalagaev
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Correspondence to I. I. Grinval’d.

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Original Russian Text © I.I. Grinval’d, A.N. Artemov, I.V. Bodrikov, L.I. Bazhan, I.Yu. Kalagaev, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 7, pp. 1130–1132.

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Grinval’d, I.I., Artemov, A.N., Bodrikov, I.V. et al. Intramolecular donor-acceptor interaction in stilbene and styrene π-complexes with tricarbonylchromium. Observation in the IR spectra. Russ J Gen Chem 79, 1487–1489 (2009). https://doi.org/10.1134/S1070363209070135

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  • DOI: https://doi.org/10.1134/S1070363209070135

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