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Acid-base and tautomeric equilibria of fluorescein dyes in water micellar solutions of zwitterionic sulfobetaine surfactant

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Abstract

Ionization constants of fluorescein and six its derivatives in water micellar solutions of zwitterionic surfactant, N-cetyl-N,N-dimethyl-3-ammonium-1-propanesulfonate were evaluated spectrophotometrically. On the basis of absorption spectra of dyes conclusions concerning the tautomerism of molecular and ionic forms were made and the relationships between the pK a values were explained.

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Authors and Affiliations

  1. Karazin Khar’kov National University, pl. Svobody 4, Khar’kov, 61077, Ukraine

    N. A. Vodolazkaya, P. V. Shakhova & N. O. Mchedlov-Petrosyan

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  1. N. A. Vodolazkaya
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  2. P. V. Shakhova
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  3. N. O. Mchedlov-Petrosyan
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Correspondence to N. O. Mchedlov-Petrosyan.

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Original Russian Text © N.A. Vodolazkaya, P.V. Shakhova, N.O. Mchedlov-Petrosyan, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 7, pp. 1081–1089.

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Vodolazkaya, N.A., Shakhova, P.V. & Mchedlov-Petrosyan, N.O. Acid-base and tautomeric equilibria of fluorescein dyes in water micellar solutions of zwitterionic sulfobetaine surfactant. Russ J Gen Chem 79, 1437–1445 (2009). https://doi.org/10.1134/S1070363209070068

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  • DOI: https://doi.org/10.1134/S1070363209070068

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