Skip to main content
SpringerLink
Log in

Transformation of the condensation products of 2-acylamino-3,3-dichloroacrylonitriles with imidazole into pyrazolo[1,5-a]pyrimidine derivatives

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Successive treatment of accessible 2-acylamino-3,3-dichloroacrylonitriles with imidazole and hydrazine hydrate led to the formation of 4-acylamino-3(5)-amino-5(3)-(1H-imidazol-1-yl)pyrazoles, and condensation of the latter with acetylacetone afforded 3-acylamino-2-(1H-imidazol-1-yl)-5,7-dimethylpyrazolo [1,5-a]pyrimidines whose structure was reliably determined by X-ray analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Drach, B.S., Sviridov, E.P., Kisilenko, A.A., and Kirsanov, A.V., Zh. Org. Khim., 1973, vol. 9, no. 9, p. 1818.

    CAS  Google Scholar 

  2. Drach, B.S., Sviridov, E.P., and Lavrenyuk, T.Ya., Zh. Org. Khim., 1974, vol. 10, no. 6, p. 1271.

    CAS  Google Scholar 

  3. Schweizer, E.E., Hayes, J.E., Rheingold, A., and Wei Xu, J. Org. Chem., 1987, vol. 52, p. 1810.

    Article  CAS  Google Scholar 

  4. Tian Li and Wang Da-Xiang, Acta Crystallogr., Sect. E, 2005, vol. 61, no. 7, p. 1286.

    Article  Google Scholar 

  5. Sheldrick, G.M., SHELX97. Program for the Solution of Crystal Structure, Gottingen: Univ. of Gottingen, 1997.

    Google Scholar 

  6. Sheldrick, G.M., SHELX97. Program for the Refinement of Crystal Structure, Gottingen: Univ. of Gottingen, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Bioorganic and Petroleum Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 1, Kiev, 02660, Ukraine

    A. P. Kozachenko, O. V. Shablykin, A. N. Vasilenko & V. S. Brovarets

  2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02660, Ukraine

    E. B. Rusanov

Authors
  1. A. P. Kozachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Shablykin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. B. Rusanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Vasilenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. S. Brovarets
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Brovarets.

Additional information

Original Russian Text © A.P. Kozachenko, O.V. Shablykin, E.B. Rusanov, A.N. Vasilenko, V.S. Brovarets, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 5, pp. 824–828.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kozachenko, A.P., Shablykin, O.V., Rusanov, E.B. et al. Transformation of the condensation products of 2-acylamino-3,3-dichloroacrylonitriles with imidazole into pyrazolo[1,5-a]pyrimidine derivatives. Russ J Gen Chem 79, 996–1000 (2009). https://doi.org/10.1134/S1070363209050223

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363209050223

Keywords

Search

Navigation