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Synthesis and spectral characteristics of a novel heterometallic binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine

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Abstract

Binuclear bridged complexes [(bpy)2Ru(μ-bptz)Re(CO)3·(Hlg)](X)2 [bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; Hlg = Cl, X = BF4 or Hlg = Br, X = NO3]. Were synthesized and studied by mass spectrometry and infrared and electronic spectroscopy. The complexes give a strong long-wave band in the electronic absorption spectrum. The spectra were interpreted on the basis of TD DFT quantum-chemical calculations.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    V. V. Pakal’nis, A. Yu. Sokolov, A. A. Slisenko, M. E. Borovitov, S. P. Tunik & O. V. Sizova

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  1. V. V. Pakal’nis
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  2. A. Yu. Sokolov
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  3. A. A. Slisenko
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  4. M. E. Borovitov
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  5. S. P. Tunik
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  6. O. V. Sizova
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Correspondence to V. V. Pakal’nis.

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Original Russian Text © V.V. Pakal’nis, A.Yu. Sokolov, A.A. Slisenko, M.E. Borovitov, S.P. Tunik, O.V. Sizova, 2009, published in Zhurnal Obshchei Khimii, 2009, vol. 79, No. 5, pp. 808–812.

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Pakal’nis, V.V., Sokolov, A.Y., Slisenko, A.A. et al. Synthesis and spectral characteristics of a novel heterometallic binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine. Russ J Gen Chem 79, 980–984 (2009). https://doi.org/10.1134/S1070363209050193

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  • DOI: https://doi.org/10.1134/S1070363209050193

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