Abstract
Effect of dimethylsulfoxide additives on the kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in benzene is studied. A strong effect of the solvent on the process rate and activation parameters is revealed. The relation of the molecular structure of the interacting molecules to their reactivity is demonstrated.
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Original Russian Text © O.A. Petrov, N.V. Chizhova, G.V. Osipova, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 4, pp. 676–681.
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Petrov, O.A., Chizhova, N.V. & Osipova, G.V. Kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in a system benzene-dimethylsulfoxide. Russ J Gen Chem 79, 839–844 (2009). https://doi.org/10.1134/S1070363209040264
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DOI: https://doi.org/10.1134/S1070363209040264