Skip to main content
SpringerLink
Log in

Amorphous perfluorinated membrane materials: Structure, properties and application

  • Supplement: Rossiiskii Khimicheskii Zhurnal-Zhurnal Rossiiskogo Khimicheskogo Obshchestva im. D.I. Mendeleeva (Russian Chemistry Journal)
  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The structure and properties of glassy amorphous perfluorinated polymers are considered with an emphasis of their use as membrane material. The results of the study of free volume in these polymers and simulation of their nanostructure are discussed. The perfluorinated polymers are featured by unusual thermodynamic properties, so the influence of these properties on the parameters of the membranes based on them is examined. In conclusion, various applications of the membranes based on the perfluorinated polymers (predominantly amorphous Teflon AF) in separation processes are described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. US Patent no. 2 230 654, 1941.

  2. US Patent no. 3 978 030, 1976.

  3. Merkel, T.C., Pinnau, I., Prabhakar, R., and Freeman, B.D., in: Materials Science of Membranes for Gas and Vapor Separation, Yampolskii,, Yu., Pinnau, I., and Freeman, B.D., Eds., Chichester: Wiley 2006, p. 251.

    Chapter  Google Scholar 

  4. Merkel, T.C., Bondar, V.I., Nagai, K., Freeman, B.D., and Yampolskii, Yu., Macromolecules, 1999, vol. 32, p. 8427.

    Article  CAS  Google Scholar 

  5. Merkel, T.C., Bondar, V.I., Nagai, K., and Freeman, B.D., Macromolecules, 1999, vol. 32, p. 370.

    Article  CAS  Google Scholar 

  6. Belov, N., Yampolskii, Yu., and Coughlin, M.C., Macromolecules, 2006, vol. 39, p. 1797.

    Article  CAS  Google Scholar 

  7. Song, W., Rossky, P.J., and Marconcelly, M., J. Chem. Phys., 2003, vol. 119, p. 9145.

    Article  CAS  Google Scholar 

  8. Mulder, M., Basic Principles of Membrane Technology. Translated under the title Vvedenie v membrannuyu tekhnologiyu, Moscow: Mir, 1999.

    Google Scholar 

  9. US Patent no. 5 051 114, 1991.

  10. Resnick, P.R. and Buck, W.H., in: Modern Fluoropolymers: High Performance Polymers for Diverse Applications, Scheirs, J., Ed., Chichester: Wiley, 1997, p. 397.

    Google Scholar 

  11. US Patent no. 5 883 177, 1999.

  12. US Patent no. 4 910 276, 1990,.

  13. Prabhakar, R.S., Freeman, B.D., and Roman, I., Macromolecules, 2004, vol. 37, p. 7688.

    Article  CAS  Google Scholar 

  14. Jansen, J.C., Macchione, M., and Drioli, E., J. Membr. Sci., 2007, vol. 287, p. 132.

    Article  CAS  Google Scholar 

  15. Alentiev, A.Yu., Yampolskii, Yu.P., Shantarovich, V.P., Nemser, S.M., and Plate, N.A., J. Membr. Sci., 1997, vol. 126, p. 123.

    Article  CAS  Google Scholar 

  16. Arcella, V., Brinati, G., Colaianna, P., Sanguineti, A., Gordano, A., Clarizia, G., Molinari, R., and Drioli, E., Abstarct of Papers, Ravello Conf. on “New Frontiers for Catalytic Membrane Reactors and Other Membrane Systems,” Italy, 1999, p. 102.

  17. Alent’ev, A.Yu., Doctorate Sci. (Chem.) Dissertation, Moscow, 2003.

  18. US Patent no. 3 308 107, 1967.

  19. Pinnau, I. and Toy, L.G., J. Membr. Sci., 1996, vol. 109, p. 125.

    Article  CAS  Google Scholar 

  20. Panshin, Yu.A., Malkevich, S.G., and Dunaevskaya, Ts.S., Ftoroplasty (Fluoroplasts), Leningrad: Khimiya, 1978.

    Google Scholar 

  21. Bondi, A., Physical Properties of Molecular Crystals, Liquids and Glasses, New York: Wiley, 1968.

    Google Scholar 

  22. Bondar, V.I., Freeman, B.D., and Yampolskii, Yu.P., Macromolecules, 1999, vol. 32, p. 6163.

    Article  CAS  Google Scholar 

  23. Yampol’skii, Yu.P., Usp. Khim., 2007, vol. 76, p. 66.

    Google Scholar 

  24. Golemme, A.G., Nagy, J.B., Fonseca, A., Algieri, C., and Yampolskii, Yu., Polymer, 2003, vol. 44, p. 5039.

    Article  CAS  Google Scholar 

  25. Yampolskii, Yu., Shantarovich, V., Chernyakovskii, F., Kornilov, A., and Plate, N., J. Appl. Polym. Sci., 1993, vol. 47, p. 85.

    Article  CAS  Google Scholar 

  26. Yampolskii, Yu., Korikov, A., Shantarovich, V., Nagai, K., Freeman, B.D., Masuda, T., Teraguchi, M., and Kwak, G., Macromolecules, 2001, vol. 34, p. 1788.

    Article  CAS  Google Scholar 

  27. Finkelshtein, E., Makovetskii, K., Gringolts, M., Rogan, Yu., Golenko, T., Starannikova, L., Yampolskii, Yu., Shantarovich, V., and Suzuki, T., Ibid., 2006, vol. 39, p. 7022.

    Article  CAS  Google Scholar 

  28. Shantarovich, V.P., Kevdina, I.B., Yampolskii, Yu.P., and Alentiev, A.Yu., Ibid., 2000, vol. 33, p. 7453.

    Article  CAS  Google Scholar 

  29. Alentiev, A.Yu., Shantarovich, V.P., Merkel, T.C., Bondar, V.I., Freeman, B.D., and Yampolskii, Yu.P., Ibid., 2002, vol. 35, p. 9513.

    Article  CAS  Google Scholar 

  30. Dlubek, G., Eichler, S., Hübner, C., and Nagel, C., Nucl. Instrum. Methods Phys. Res. B, 1999, vol. 149, p. 501.

    Article  CAS  Google Scholar 

  31. Hofmann, D., Entrialgo-Castano, M., Lerbret, A., Heuchel, M., and Yampolskii, Yu., Macromolecules, 2003, vol. 36, p. 8528.

    Article  CAS  Google Scholar 

  32. Wang, X.-Y., Lee, K.M., Lu, Y., Stone, M.T., Sanchez, I.C., and Freeman, B.D., Polymer, 2004, vol. 45, p. 3907.

    Article  CAS  Google Scholar 

  33. Merkel, T.C., Bondar, V., Nagai, K., and Freeman, B.D., J. Polym. Sci.: Part B: Polym. Phys., 2000, vol. 38, p. 273.

    Article  CAS  Google Scholar 

  34. Nagai, K., Masuda, T., Nakagawa, T., Freeman, B.D., and Pinnau, I., Progr. Polym. Sci., 2001, vol. 26, p. 721.

    Article  CAS  Google Scholar 

  35. Tokarev, A.V., Bondarenko, G.N., and Yampol’skii, Yu.P., Vysokomol. Soed., Part A, 2007, vol. 49, p. 1510.

    CAS  Google Scholar 

  36. Hildebrnd, J.H., Prausnitz, J.M., and Scott, R.L., Regular and Related Solutions, New York: Van Nostrand Reinhold, 1970.

    Google Scholar 

  37. Prabhakar, R.S., De Angelis, M.G., Sarti, G.C., Freeman, B.D., and Coughlin, M.C., Macromolecules, 2005, vol. 38, p. 7043.

    Article  CAS  Google Scholar 

  38. Starannikova, L. E., Belov N. A., Shantarovich, V.P., Suzuki, T., Golenko, T.G., Makovetskii, K.L., and Yampol’skii, Yu.P., Vysokomol. Soed., Part A, 2007, vol. 49, p. 786.

    CAS  Google Scholar 

  39. Kharitonov, A.P., Doctorate Sci. (Phys.-Math.) Dissertation, Chernogolovka, 2005.

  40. US Patent no.5 051 113, 1991.

  41. US Patent no. 5 053 059, 1991.

  42. US Patent no. 5 147 417, 1992.

  43. US Patent no. 6 126 721, 2000.

  44. US Patent no. 5 902 747, 1999.

  45. Belyaev, A.A., Yampolskii, Yu.P., Starannikova, L.E., Polyakov, A.M., Clarizia, G., Drioli, E., Marigliano, G., and Barbieri, G., Fuel Processing Technology, 2003, vol. 80, p. 119.

    Article  CAS  Google Scholar 

  46. Yampolskii, Yu., Polyakov, A., and Drioli, E.,. Abstarct of Papers, 1st Workshop Italy-Russia “Membrane technology for a sustainable industrial production,” Italy, 2003.

  47. Nemser, S.M., Abstarct of Papers, 16th Ann Membrane Technol/Separation Planning Conf., USA, 1998.

  48. Yampol’skii, Yu., Vinogradskii, L., Abstract of Papers, “High Intense Physical Factors in Medicine, Biology, and Ecology,” Sarov, 2004.

  49. Yampol’skii, Yu.P., Polyakov, A.M., and Alent’ev, A.Yu., Vysokomol. Soed., Part A, 2005, vol. 47, p. 1528.

    Google Scholar 

  50. Polyakov, A.M., Starannikova, L.E., and Yampolskii, Yu.P., J. Membr. Sci., 2003, vol. 216, p. 241.

    Article  CAS  Google Scholar 

  51. Polyakov, A.M., Starannikova, L.E., and Yampolskii, Yu.P., Ibid., 2004, vol. 238, p. 21.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Leninskii pr. 29, Moscow, 119991, Russia

    Yu. P. Yampolskii

Authors
  1. Yu. P. Yampolskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. P. Yampolskii.

Additional information

Original Russian Text © Yu.P. Yampolskii, 2009, published in Rossiiskii Khimicheskii Zhurnal, 2009, Vol. 52, No. 3, pp. 123–130.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yampolskii, Y.P. Amorphous perfluorinated membrane materials: Structure, properties and application. Russ J Gen Chem 79, 657–665 (2009). https://doi.org/10.1134/S1070363209030475

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363209030475

Keywords

Search

Navigation