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Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides

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Abstract

On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl) diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, South State University, Prosp. Stachki 194/2, Rostov on Don, 344090, Russia

    A. S. Burlov, S. A. Mashchenko, O. A. Ivashchenko, A. I. Uraev, M. S. Korobov, I. G. Borodkina & A. D. Garnovskii

  2. South Scientific Center of Russian Academy of Sciences, Rostov on Don, Russia

    D. A. Garnovskii

  3. Invek RD Ltd., Rostov on Don, Russia

    G. G. Chigarenko & A. G. Ponomarenko

Authors
  1. A. S. Burlov
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  2. S. A. Mashchenko
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  3. O. A. Ivashchenko
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  4. D. A. Garnovskii
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  5. A. I. Uraev
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  6. M. S. Korobov
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  7. I. G. Borodkina
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  8. G. G. Chigarenko
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  9. A. G. Ponomarenko
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  10. A. D. Garnovskii
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Correspondence to D. A. Garnovskii.

Additional information

Original Russian Text © A.S. Burlov, S.A. Mashchenko, O.A. Ivashchenko, D.A. Garnovskii, A.I. Uraev, M.S. Korobov, I.G. Borodkina, G.G. Chigarenko, A.G. Ponomarenko, A.D. Garnovskii, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 3, pp. 412–418.

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Burlov, A.S., Mashchenko, S.A., Ivashchenko, O.A. et al. Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides. Russ J Gen Chem 79, 401–407 (2009). https://doi.org/10.1134/S1070363209030128

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  • DOI: https://doi.org/10.1134/S1070363209030128

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