Skip to main content
SpringerLink
Log in

New polyunsaturated silahydrocarbons

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

12-Membered highly unsaturated macrocyclic silahydrocarbon containing exocyclic methyl and benzyl groups is synthesized by the reaction of benzylmethyldi(bromomagnesiumethynyl)silane with dimethyldichlorosilane. Hydrosilylation of benzyl(triethynyl)silane with trichlorosilane with subsequent reaction of the formed adduct with trimethylsilylmagnesium bromide leads to the spherical dendrimer (NC = 3) containing the benzyl group at the central Si atom, -CH=CH- groups in the inner sphere and numerous triple bonds on periphery. NMR spectra of the obtained compounds were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Voronkov, M., Yarosh, O., and Zhilitskaja, L., Phosphorus, Sulfur and Silicon, 1992, vol. 65, p. 33.

    Article  CAS  Google Scholar 

  2. Voronkov, M.G., Yarosh, O.G, and Turkina, G.Yu., J. Organomet. Chem., 1995, vol. 491, nos 1–2, p. 215.

    Article  CAS  Google Scholar 

  3. Yarosh, O.G., Voronkov, M.G., and Brodskaya, E.I., Russ. Chem. Rev., 1995, vol. 64, no. 9, p. 839.

    Article  Google Scholar 

  4. Yarosh, O.G., Zhilitskaya, L.V., Istomina, E.E., Yarosh, N.K., Albanov, A.I., and Voronkov, M.G., Russ. J. Gen. Chem., 2005, vol. 75, no. 7, p 1094.

    Article  CAS  Google Scholar 

  5. Zhilitskaya, L.V., Istomina, E.E., Yarosh, N.O., and Voronkov, M.G., Russ. J. Gen. Chem., 2006, vol. 76, no. 8, p 1261.

    Article  CAS  Google Scholar 

  6. Zhilitskaya, L.V., Istomina, E.E., Yarosh, N.O., Voronkov, M.G., Albanov, A.I., and Yarosh, O.G., Russ. J. Gen. Chem., 2006, vol. 76, no. 12, p. 1864.

    Article  CAS  Google Scholar 

  7. Zhilitskaya, L.V., Yarosh, N.K., Istomina, E.E., and Voronkov, M.G., Russ. J. Gen. Chem. 2007, vol. 77, no. 10, p. 1718.

    Article  CAS  Google Scholar 

  8. Zhilitskaya, L.V., Yarosh, N.K., Istomina, E.E., Voronkov, M.G., and Albanov, A.I., Russ. J. Gen. Chem., 2007, vol. 77, no. 11, p. 1887.

    Article  CAS  Google Scholar 

  9. Zhilitskaya, L.V., Yarosh, N.O., and Voronkov, M.G., Russ. J. Gen. Chem., 2008, vol. 78, no. 10, p. 1889.

    Article  CAS  Google Scholar 

  10. Zhilitskaya, L.V., Yarosh, N.K., Yarosh, N.O., and Voronkov, M.G., Russ. J. Gen. Chem., 2008, vol. 78, no. 1, p. 69.

    Article  CAS  Google Scholar 

  11. Yarosh, O.G., Zhilitskaya, L.V., Yarosh, N.K., Albanov, A.I., and Voronkov, M.G., Russ. J. Gen. Chem., 2004, vol. 74, no. 10, p. 1492.

    Article  CAS  Google Scholar 

  12. Semchikov, Yu.D., Soros. Obraz. Zh., 1998, no. 12, p. 45.

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    L. V. Zhilitskaya, N. O. Yarosh, N. K. Yarosh & M. G. Voronkov

Authors
  1. L. V. Zhilitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. O. Yarosh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. K. Yarosh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. G. Voronkov.

Additional information

Original Russian Text © L.V. Zhilitskaya, N.O. Yarosh, N.K. Yarosh, M.G. Voronkov, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 3, pp. 393–395.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhilitskaya, L.V., Yarosh, N.O., Yarosh, N.K. et al. New polyunsaturated silahydrocarbons. Russ J Gen Chem 79, 383–385 (2009). https://doi.org/10.1134/S1070363209030086

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363209030086

Keywords

Search

Navigation