Skip to main content
SpringerLink
Log in

Unusual transformations of difluorosilanone F2Si=O

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The structure and properties of fluorosilicon polymer (fluorosil) formed by the reaction of phenyltrifluorosilane with aliphatic alcohols have been studied by the methods of IR, 19F, 29Si NMR spectroscopy, high temperature mass-spectrometry, derivatography and atom emission analysis. Due to its high reactivity, this polymer readily reacts with glass of the reaction vessel extracting the ions of all metals entering into its composition. Fluorosil formed in a quartz, teflon or polypropylene reactors is characterized by low stability and is slowly decomposed to SiF4 and SiO2. Apparently, fluorosil is the product of incorporation of SiF4 into the SiO2 matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Voronkov, M.G., Chernov, N.F., and Perlova, E.M., Zh. Obshch. Khim., 1987, vol. 57, no. 1, p. 161.

    CAS  Google Scholar 

  2. Voronkov, M.G., Chernov, N.F., and Perlova, E.M., J. Organomet. Chem., 1988, vol. 341, nos. 1–3, p. 225.

    Article  CAS  Google Scholar 

  3. Voronkov, M.G., Boyarkina, E.V., Gebel, I.A., Albanov, A.I., and Basenko, S.V., Russ. J. Gen. Chem., 2005, vol. 75, no. 12, p., 1927.

    Article  CAS  Google Scholar 

  4. Voronkov, M.G., Abstarct of Papers, 10 Vserossiiskaya konferentsiya “Kremniiorganicheskie soedineniya: sintez, svoistva, primenenie” (10th All-Russian Conf. “Organosilicon Compounds: Synthesis, Properties, and Use”), Moscow, 2005, p. 1.

  5. Voronkov, M.G., Trofimova, O.M., Grebneva, E.A., Bolgova, Yu.I., Albanov, A.I., Chipanina, N.N., and Chernov, N.F., Abstarct of Papers, 14 Int. Symp. on Organosilicon Chemistry, Germany, 2005, p. 199.

  6. Voronkov, M.G., Trofimova, O., M., Chernov, N.F., Albanov, A.I., Chipanina, N.N., and Grebneva, E.A., Appl. Organomet. Chem., 2005, vol., 19, no. 4, p. 538.

    Article  CAS  Google Scholar 

  7. Voronkov, M.G., Grebneva, E.A., Trofimova, O.M., Chernov, N.F., Albanov, A.I., and Chipanina, N.N., Dokl. Chem,, 2006, vol. 409,no. 2, p. 139.

    Article  CAS  Google Scholar 

  8. Voronkov, M.G., Albanov, A.I., Grebneva, E.A., Trofimova, O.M., Chernov, N.F., and Chipanina, N.N., Russ. J. Gen. Chem., 2006, vol. 76, no. 12, p. 1854.

    Article  CAS  Google Scholar 

  9. Voronkov, M.G., Grebneva, E.A., Trofimova, O.M., Chernov, N.F., Albanov, A.I., and Chipanina, N.N., Abstracts of Papers, 7 Vserossiiskaya konferentsiya “Khimiya ftora” (7th All-Russian Conf. “Chemistry of Fluorine,” Moscow, 2006, p. 28.

  10. Grebneva, E.A., Trofimova, O.M., Chernov, N.F., Albanov, A.I., Chipanina, N.N., and Voronkov, M.G., Abstracts of Papers, Int. Conf. Org. Chem. “Organic Chemistry from Butlerov and Beilstein till the Pesent,” St. Petersburg, 2006, p. 495.

  11. Grebneva, E.A., Trofimova, O.M., and Voronkov, M.G., Abstracts of Papers, IV All-Russian Scient. Youth Conf. “Inder Σ Mark,” Omsk, 2007, p. 93.

  12. Schnöckel, H., J. Mol. Struct., 1980, vol. 65, p. 115.

    Article  Google Scholar 

  13. Larson, J.W. and McMahon, T.B., Inorg. Chem., 1987, vol. 26, no. 24, p. 4018.

    Article  CAS  Google Scholar 

  14. Langer, H.G., USA Patent, 3453079, 19690701., C.A., 1969, vol. 71, 40881k.

  15. Shinmei, M., Imai, T., Yokokawa, T., and Masson, C.R., Proc. Int. Symp. Molten Salt Chem. Technol., 1983, p. 133.

  16. Shinmei, M., Imai, T., Yokokawa, T., and Masson, C.R., J. Chem. Thermodyn., 1986, vol. 18, no. 3, p. 241.

    Article  CAS  Google Scholar 

  17. Sharp, K.G. and Margrave, J.L., J. Inorg. Nucl. Chem., 1971, vol. 33, no. 9, p. 2813.

    Article  CAS  Google Scholar 

  18. Grosse-Ruyken, H., Angew. Chem., 1950, vol.. 62, no. 4, p. 89.

    Google Scholar 

  19. Goubeau, V.J. and Grosse-Ruyken, H., Z. Anorg. Allg. Chem., 1951, vol. 264, p. 230.

    Article  CAS  Google Scholar 

  20. Radtsig, V.A. and Senchenya, I.N., Izv. Akad. Nauk. Ser. Khim., 1996, no. 8, p., 1951.

  21. Kudo, T. and Nagase, S., J. Organomet. Chem., 1983, vol. 253, no. 3, p. C23.

    Article  CAS  Google Scholar 

  22. Breidung, J. and Thiel, W., Z. Anorg. Allg. Chem., 2000, vol. 626, p. 362.

    Article  CAS  Google Scholar 

  23. Hargittai, M. and Reffy, B., J. Phys. Chem., A., 2004, vol. 108, no. 46, p. 10194.

    Article  CAS  Google Scholar 

  24. Alikhani, M.E. and Silvi, B., J. Comput. Chem., 1998, vol. 19, no. 11, p. 1205.

    Article  CAS  Google Scholar 

  25. Jalbout, A.F. and El-Nahas, A.M., J. Mol. Struct. Theochem., 2004, vol. 671, nos. 1–3, p. 125.

    Article  CAS  Google Scholar 

  26. Stewart, J.P., Gordon, M.S., and Frank, J., Phosphorus, Sulfur and Silicon and the Related Elements, 1990, vol. 47, nos. 1–2, p. 105.

    Article  CAS  Google Scholar 

  27. Chernyshev, E.A., Mudrova, N.A., Krasnova, T.L., Ushakov, Yu.M., Petrunin, A.B., and Kuznetsova, M.G., Zh. Obshch. Khim., 1987, vol. 57, no. 3, p. 1725.

    CAS  Google Scholar 

  28. Chernyshev, E.A., Krasnova, T.L., Mudrova, N.A., Golovkin, A.V., and Kuznetsova, M.G., Zh. Obshch. Khim., 1992, vol. 62, no. 6, p. 1308.

    CAS  Google Scholar 

  29. Voronkov, M.G., Russ., J. Gen. Chem., 1998, vol. 68, no. 6, p. 901.

    CAS  Google Scholar 

  30. Zabalov, M.V., Karlov, S.S., Lemenovskii, D.A., and Zaitseva, G.S., Russ. Chem. Bull., 2006, vol. 55, no. 5, p. 775.

    Article  CAS  Google Scholar 

  31. Spravochnik Khimika (Chemist’s Companion), Nikol’skii, B.P., Ed., Moscow: Khimiya, 1996, vol. 5, p. 333.

    Google Scholar 

  32. Sokolov, B.A., Grishko, A.N., Lavrova, K.F., and Kagan, G.I., Sintez i svoistva monomerov (Synthesis and Properties of Monopolymers), Moscow: Nauka, 1964, p. 152.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. G. Voronkov, S. V. Basenko, E. V. Boyarkina, E. F. Kalistratova, S. I. Lopatin, I. A. Gebel & L. E. Zelenkov

Authors
  1. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Basenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Boyarkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. F. Kalistratova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. I. Lopatin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. A. Gebel
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. L. E. Zelenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. G. Voronkov.

Additional information

Original Russian Text © M.G. Voronkov, S.V. Basenko, E.V. Boyarkina, E.F. Kalistratova, S.I. Lopatin, I.A. Gebel, L.E. Zelenkov, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 2, pp. 227–232.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Voronkov, M.G., Basenko, S.V., Boyarkina, E.V. et al. Unusual transformations of difluorosilanone F2Si=O. Russ J Gen Chem 79, 215–220 (2009). https://doi.org/10.1134/S107036320902008X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107036320902008X

Keywords

Search

Navigation