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Synthesis and structure of (C=O→Si←O′=C′)bis(2-methyl-4-oxopyran-3-yloxy)difluoro-(λ6)siliconium

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Abstract

A new six-coordinate silicon compound, (C=O→Si←O′=C′)bis(2-methyl-4-oxopyran-3-yloxy)-difluoro(λ6)siliconium, containing two five-membered rings closed by C=O→Si coordination bonds, forms o protodesilylation trifluoro(phenyl)silane with 3-hydroxy-2-methylpyran-4-one (maltol). According to multinuclear NMR and IR spectral data and quantum-chemical calculations, the silicon atom in this compound has an octahedral environment with two cis-arranged C=O→Si bonds

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    T. N. Aksamentova, N. N. Chipanina, M. G. Voronkov, E. A. Grebneva, A. I. Albanov, O. M. Trofimova, S. A. Mukha & B. G. Sukhov

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  1. T. N. Aksamentova
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  2. N. N. Chipanina
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  3. M. G. Voronkov
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  4. E. A. Grebneva
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  5. A. I. Albanov
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  6. O. M. Trofimova
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  7. S. A. Mukha
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  8. B. G. Sukhov
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Correspondence to O. M. Trofimova.

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Original Russian Text © T.N. Aksamentova, N.N. Chipanina, M.G. Voronkov, E.A. Grebneva, A.I. Albanov, O.M. Trofimova, S.A. Mukha, B.G. Sukhov, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 1, pp. 100–105.

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Aksamentova, T.N., Chipanina, N.N., Voronkov, M.G. et al. Synthesis and structure of (C=O→Si←O′=C′)bis(2-methyl-4-oxopyran-3-yloxy)difluoro-(λ6)siliconium. Russ J Gen Chem 79, 98–103 (2009). https://doi.org/10.1134/S1070363209010150

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  • DOI: https://doi.org/10.1134/S1070363209010150

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