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Reaction of palladium bisacetylacetonate with elemental phosphorus. Effect of water on the composition of palladium phosphides

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Abstract

Reaction of palladium bisacetylacetonate with elemental phosphorus in an inert atmosphere is shown to proceed as a redox process forming palladium phosphides of different compositions: PdP2, Pd5P2, Pd4,8P, and Pd12P3,2. The conversion of Pd(acac)2 and the composition of palladium phosphides formed in benzene is established to be affected by water. A tentative scheme of the formation of palladium phosphides is suggested.

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Authors and Affiliations

  1. Irkutsk State University, ul. K. Marksa 1, Irkutsk, 664003, Russia

    L. B. Belykh, N. I. Skripov, L. N. Belonogova, A. V. Rokhin & F. K. Shmidt

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  1. L. B. Belykh
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  2. N. I. Skripov
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  3. L. N. Belonogova
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  4. A. V. Rokhin
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  5. F. K. Shmidt
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Correspondence to L. B. Belykh.

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Original Russian Text © L.B. Belykh, N.I. Skripov, L.N. Belonogova, A.V. Rokhin, F.K. Shmidt, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 1, pp. 94–99.

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Belykh, L.B., Skripov, N.I., Belonogova, L.N. et al. Reaction of palladium bisacetylacetonate with elemental phosphorus. Effect of water on the composition of palladium phosphides. Russ J Gen Chem 79, 92–97 (2009). https://doi.org/10.1134/S1070363209010149

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  • DOI: https://doi.org/10.1134/S1070363209010149

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