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Cooperative effect of hydrogen bonds in the complexes of aliphatic alcohols with proton acceptors in chloroform

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Abstract

Effect of solvation on the frequency of stretching vibrations of O-H groups of aliphatic alcohols in complexes with acetonitrile, dimethyl sulfoxide, diethyl ether, pyridine, tetrahydrofuran, and triethylamine in various media was studied by IR spectroscopy. We found that the strength of hydrogen bonds in the studied complexes increased considerably at the interaction with chloroform as a solvent. The contribution of cooperative effect was estimated. The enthalpies of cooperative effect in the complexes consisting of three different molecules are estimated for the first time.

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Authors and Affiliations

  1. Butlerov Institute of Chemistry, Kazan State University, ul. Kremlyevskaya 18, Kazan, 420008, Tatarstan, Russia

    M. A. Varfolomeev, D. I. Abaidullina, I. T. Rakipov & B. N. Solomonov

Authors
  1. M. A. Varfolomeev
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  2. D. I. Abaidullina
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  3. I. T. Rakipov
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  4. B. N. Solomonov
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Correspondence to M. A. Varfolomeev.

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Original Russian Text © M.A. Varfolomeev, D.I. Abaidullina, I.T. Rakipov, B.N. Solomonov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 12, pp. 1937–1946.

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Varfolomeev, M.A., Abaidullina, D.I., Rakipov, I.T. et al. Cooperative effect of hydrogen bonds in the complexes of aliphatic alcohols with proton acceptors in chloroform. Russ J Gen Chem 78, 2283–2292 (2008). https://doi.org/10.1134/S1070363208120013

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  • DOI: https://doi.org/10.1134/S1070363208120013

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