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Percolation models of grain boundary wetting in polycrystalline materials

  • Supplement: Rossiiskii Khimicheskii Zhurnal-Zhurnal Rossiiskogo Khimicheskogo Obshchestva im. D.I. Mendeleeva (Russian Chemistry Journal)
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Abstract

A model is proposed accounting for grain boundary (GB) wetting in polycrystals. Liquid penetration into GB planes, triple lines, and quadruple points is analyzed. The GB wetting condition (Gibbs-Smith criterion) is generalized by introducing a parameter defined as “characteristic free energy.” In order to find critical values of interfacial/GB energy ratio corresponding to an infinite cluster formation, the percolation theory has been used. Model estimates are consistent with the experimentally observed topology of additives in polycrystalline zinc.

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Authors and Affiliations

  1. High National Chemical School of France, Paris, France

    P. M. Volovich

  2. High National School of Arts and Crafts, Aix-en-Provence, France

    L. Barrallier

  3. Lomonosov Moscow State University, str. 3, Leninskie Gory 1, Moscow, 119992, Russia

    Z. N. Skvortsova & V. Yu. Traskin

Authors
  1. P. M. Volovich
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  2. L. Barrallier
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  3. Z. N. Skvortsova
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  4. V. Yu. Traskin
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Correspondence to V. Yu. Traskin.

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Original Russian Text © P.M. Volovich, L. Barrallier, Z.N. Skvortsova, V.Yu. Traskin, 2008, published in Rossiiskii Khimicheskii Zhurnal, 2008, Vol. 52, No. 1, pp. 13–20.

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Volovich, P.M., Barrallier, L., Skvortsova, Z.N. et al. Percolation models of grain boundary wetting in polycrystalline materials. Russ J Gen Chem 78, 2182–2190 (2008). https://doi.org/10.1134/S107036320811039X

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  • DOI: https://doi.org/10.1134/S107036320811039X

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